- (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
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| Name |
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate |
EINECS | N/A |
| CAS No. | 210057-23-1 | Density | N/A |
| PSA | 27.18000 | LogP | 8.72020 |
| Solubility | Insoluble in water | Melting Point |
N/A |
| Formula | C26H40P2Rh.BF4 | Boiling Point | 415 °C at 760 mmHg |
| Molecular Weight | 604.26 | Flash Point | 216.3 °C |
| Transport Information | N/A | Appearance | red or red-brown crystalline powder |
| Safety | 24/25 | Risk Codes | 36/37/38 |
| Molecular Structure |
![Molecular Structure of 210057-23-1 ((-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate)](http://www.lookchem.com/300w/201001/img/210057-23-1.jpg_ms)
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Hazard Symbols | N/A |
| Synonyms |
(-)-1,2-BIS((2R,5R)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE(I)TETRAFLUOROBORATE;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;Bisdimethylphospholanobenzenecyclooctadienerho;1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate |
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Specification
The systematic name of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate is (1Z,5Z)-cycloocta-1,5-diene; (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethyl-phospholane; rhodium; tetrafluoroborate . With the CAS registry number 210057-23-1, it is also named as (R,R)-Me-DUPHOS-Rh ; Bisdimethylphospholanobenzenecyclooctadienerho ; 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate . The product's categories are chiral catalysts, ligands and reagents, DuPhos/BPE, privileged ligands and complexes.
The (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate is red or red-brown crystalline powder and can be insoluble in water. It is irritating to eyes, respiratory system and skin. So people should avoid contact with skin and eyes.
The other characteristics of this product can be summarized as: (1)ACD/LogD (pH 5.5): 5.77 ; (2)ACD/LogD (pH 7.4): 5.77 ; (3)ACD/BCF (pH 5.5): 14243.49 ; (4)ACD/BCF (pH 7.4): 14243.49 ; (5)ACD/KOC (pH 5.5): 32714.95 ; (6)ACD/KOC (pH 7.4): 32714.95 ; (7)#Freely Rotating Bonds: 2 ; (8)Enthalpy of Vaporization: 64.2 kJ/mol ; (9)Vapour Pressure: 1.03E-06 mmHg at 25°C.
People can use the following data to convert to the molecule structure. SMILES: [Rh].F[B-](F)(F)F.c1cc(c(cc1)P2[C@@H](CC[C@H]2C)C)P3[C@H](C)CC[C@H]3C.C\1=C\CC/C=C\CC/1; InChI: InChI=1/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t13-,14-,15-,16-;;;/m1.../s1.
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