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2,3,5-Trimethylphenol

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Name

2,3,5-Trimethylphenol

EINECS 211-806-9
CAS No. 697-82-5 Density 0.996 g/cm3
PSA 20.23000 LogP 2.31740
Solubility insoluble in water Melting Point 92-95 °C(lit.)
Formula C9H12O Boiling Point 231.1 °C at 760 mmHg
Molecular Weight 136.194 Flash Point 103.6 °C
Transport Information UN 2430 8/PG 3 Appearance White to off-white powder
Safety 26-36/37/39-45-24/25 Risk Codes 34-36/37/38
Molecular Structure Molecular Structure of 697-82-5 (2,3,5-Trimethylphenol) Hazard Symbols CorrosiveC, IrritantXi
Synonyms

Phenol,2,3,5-trimethyl-;1-Hydroxy-2, 3,5-trimethylbenzene;1-Hydroxy-2,3,5-trimethylbenzene;

Article Data 62

2,3,5-Trimethylphenol Synthetic route

O-(4-Nitrobenzyl)-2,3,5-trimethylphenol

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With indium; ammonium chloride In ethanol for 18h; Debenzylation; Heating;100%
With indium; ammonium chloride In methanol for 18h; Heating;100%

1,2,5-Trimethyl-3-trityloxy-benzene

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With tetrahydrofuran; titanium(III) chloride; lithium for 14h; Heating;92%
312609-91-9

2,3,5-Trimethyl-(4-methylphenylsulfonyloxy)benzene

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With titanium(III) chloride; lithium In tetrahydrofuran at 25℃; for 18h; Substitution;91%
773-01-3

2,4,6-trimethylpyrylium tetrafluoroborate

70775-39-2, 5367-24-8

dimethylsulfoxonium methylide

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
In tetrahydrofuran; dimethyl sulfoxide 1.) -5 deg C, 1 h, 2.) room temperature, 7 h;80%
67-56-1

methanol

526-75-0

2,3-Dimethylphenol

A

2416-94-6

2,3,6-trimethylphenol

B

526-85-2

2,3,4-trimethylphenol

C

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
Pd-containing mordenite at 350℃;A 80%
B 5%
C 5%
67-56-1

methanol

108-68-9

3,5-Dimethylphenol

A

527-54-8

3,4,5-trimethylphenol

B

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
Pd-containing mordenite at 350℃;A 6%
B 70%
95-63-6

1,2,4-Trimethylbenzene

A

16308-92-2

2,4-dimethylbenzyl alcohol

B

700-13-0

Trimethylhydroquinone

C

496-78-6

2,4,5-trimethylphenol

D

2416-94-6

2,3,6-trimethylphenol

E

697-82-5

2,3,5-trimethylphenol

F

53957-33-8

2,5-dimethylbenzyl alcohol

Conditions
ConditionsYield
With glucose dehydrogenase; D-glucose; P450 BM3 R47S, Y51W, A330F, I401M mutant; NADPH; catalase; ascorbic acid In aq. phosphate buffer; dimethyl sulfoxide pH=7.5; Catalytic behavior; Enzymatic reaction;A 25%
B 23%
C 28%
D 5%
E 8%
F 9%
50-00-0

formaldehyd

1123-09-7

3,5-dimethyl-2-cyclohexen-1-one

660-68-4

diethyl amine hydrochloride

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With hydrogenchloride; ethanol Behandeln des Reaktionsprodukts mit HCl in Aether und Erhitzen der erhaltenen Hydrochloride unter vermindertem Druck auf 200-235grad;
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

A

527-54-8

3,4,5-trimethylphenol

B

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With bromine; 1,2,4-Trichlorobenzene
68097-90-5

3,5-dimethyl-2-piperidin-1-ylmethyl-phenol

697-82-5

2,3,5-trimethylphenol

Conditions
ConditionsYield
With calcium hydroxide
With 1,4-dioxane; copper oxide-chromium oxide at 165℃; Hydrogenolyse;

2,3,5-Trimethylphenol Chemical Properties

IUPAC Name: 2,3,5-trimethylphenol
The Molecular formula of 2,3,5-Trimethylphenol (697-82-5) : C9H12O
The Molecular Weight of  2,3,5-Trimethylphenol (697-82-5) : 136.19
Molecular Structure :
EINECS: 211-806-9
Melting point: 92-95 °C(lit.)
Boiling point: 231.1 °C at 760 mmHg
Flash point: 103.6 °C  
Density: 0.996 g/cm3 
Vapour Pressure: 0.0419 mmHg at 25°C
Storage temp.: Store in dark
Solubility: insoluble
Water Solubility: insoluble
Synonyms: ISOPSEUDOCUMENOL;2,3,5-Trimethylphenol/TMP/Isopseudocumenol; 2,3,5-Thrimethylphenol;AKOS BBS-00008093;2,3,5-trimethyl-pheno;2,3,5-TRIMETHYLPHENOL;6-HYDROXYPSEUDOCUMENE;1-Hydroxy-2,3,5-trimethylbenzene;

2,3,5-Trimethylphenol Uses

 2,3,5-Trimethylphenol (697-82-5) is used for synthesis of aromatic vitamin A acid.

2,3,5-Trimethylphenol Safety Profile

The Hazard Codes of 2,3,5-Trimethylphenol (697-82-5):   C,  Xi
The Risk Statements information of 2,3,5-Trimethylphenol (697-82-5):
34:  Causes burns 
36/37/38:  Irritating to eyes, respiratory system and skin 
The Safety Statements information of 2,3,5-Trimethylphenol (697-82-5):
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
24/25:  Avoid contact with skin and eyes 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
HazardClass: 8
PackingGroup: III
HS Code: 29071900
RIDADR: UN 2430 8/PG 3
WGK Germany: 3

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