- 2-benzylaminopyridine
- 2-BENZYLAMINOPYRIDINE HYDROCHLORIDE
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Cas Database |
| Name |
2-benzylaminopyridine |
EINECS | 230-060-5 |
| CAS No. | 6935-27-9 | Density | 1.131 g/cm3 |
| PSA | 24.92000 | LogP | 2.76670 |
| Solubility | N/A | Melting Point |
95-97 °C(lit.) |
| Formula | C12H12N2 | Boiling Point | 321.8 °C at 760 mmHg |
| Molecular Weight | 184.241 | Flash Point | 148.4 °C |
| Transport Information | N/A | Appearance | white to off-white powder |
| Safety | 26-39 | Risk Codes | 22-37/38-41 |
| Molecular Structure |
|
Hazard Symbols |
 Xn
|
| Synonyms |
Pyridine,2-(benzylamino)- (6CI,7CI,8CI);2-(Benzylamino)pyridine;N-Benzyl-2-aminopyridine;N-Benzyl-2-pyridinamine;N-Benzylpyridine-2-amine;NSC 59833; |
Article Data | 178 |
2-benzylaminopyridine Synthetic route
| Conditions | Yield |
|---|---|
| With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube; | 100% |
| With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; | 99% |
| With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; Inert atmosphere; | 99% |
| Conditions | Yield |
|---|---|
| With sodium t-butanolate In toluene at 100 - 110℃; for 24h; Buchwald-Hartwig amination; Inert atmosphere; Sealed vial; | 99% |
| With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation; | 95% |
| With copper(l) iodide; C14H16N2O; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; Sealed tube; | 93% |
| Conditions | Yield |
|---|---|
| With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; | 99% |
| With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry; | 93% |
| With tetra(n-butyl)ammonium hydroxide; copper(II) sulfate In water at 80℃; for 24h; Schlenk technique; Sealed tube; Inert atmosphere; | 80% |
| With tetramethyl ammoniumhydroxide; ethyl 2-oxocyclohexane carboxylate; copper(l) chloride In dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere; | 72% |
- 1883-96-1, 82299-15-8, 88785-73-3
N-benzylidenepyridin-2-amine
- 6935-27-9
N-benzylpyridin-2-amine
| Conditions | Yield |
|---|---|
| With Triethoxysilane; [bis(2,6-diisopropylaniline)acenaphthene]Fe(η6-toluene) at 70℃; for 18h; Schlenk technique; Inert atmosphere; Glovebox; Sealed tube; | 98% |
| With (4-Ph)Triaz(NHPiPr2)2Mn(CO)2Br; potassium tert-butylate; hydrogen In tetrahydrofuran at 50℃; under 15001.5 Torr; for 4h; Glovebox; Autoclave; Sealed tube; chemoselective reaction; | 92% |
| With sodium tetrahydroborate In tetrahydrofuran at 25℃; for 4h; | 40% |
| With sodium tetrahydroborate In methanol for 5h; Cooling; | 19.09 g |
| With [MnBr(CO)3(2-(diphenylphosphinoamino)pyridine)]; potassium tert-butylate; hydrogen In ethanol at 80℃; for 48h; Autoclave; | 50.7 mg |
- 1444866-70-9
methyl benzylpyridin-2-ylcarbamate
- 6935-27-9
N-benzylpyridin-2-amine
| Conditions | Yield |
|---|---|
| With water; sodium hydroxide In methanol for 3h; Reflux; | 98% |
- 442513-39-5
benzyl-pyridin-2-yl-carbamic acid tert-butyl ester
- 6935-27-9
N-benzylpyridin-2-amine
| Conditions | Yield |
|---|---|
| With trifluoroacetic acid In dichloromethane; water | 97% |
| With trifluoroacetic acid In dichloromethane; water at 25℃; |
| Conditions | Yield |
|---|---|
| With dibenzylphosphoramidous acid 1,1'-binaphthyl-2,2'-diyl ester; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 90℃; for 36h; | 97% |
| With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 65℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry; | 95% |
| With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; | 92% |
- 1335111-43-7
N-benzyl-N-(pyridin-2-yl)hydroxylamine
- 6935-27-9
N-benzylpyridin-2-amine
| Conditions | Yield |
|---|---|
| With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 0.5h; Inert atmosphere; | 97% |
| Conditions | Yield |
|---|---|
| With [RuCl(CO)(PPh3)(PNS-Me)]; potassium hydroxide In toluene at 100℃; for 12h; | 96% |
| With bis(5-chlorosalicylidene)hydrazone binuclear copper(I) complex; potassium hydroxide In toluene at 100℃; for 18h; | 80% |
| With aluminum (III) chloride; water In acetonitrile at 20℃; Irradiation; | 50% |
| Conditions | Yield |
|---|---|
| With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; silver trifluoromethanesulfonate In dichloromethane at 20℃; for 2h; | 93% |
| With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In neat (no solvent) at 150℃; for 0.25h; | 92% |
| With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; thiourea In toluene at 70℃; for 24h; | 91% |
2-benzylaminopyridine Chemical Properties
IUPAC Name: N-benzylpyridin-2-amine
Molecular Formula: C12H12N2
Molecular Weight: 184.2371g/mol
Appearance: white to off-white powder
EINECS: 230-060-5
Density: 1.131 g/cm3
Melting Point: 94°C to 98°C
Boiling Point: 116-131°C(0.6 mmHg),321.8 °C at 760 mmHg
Flash Point: 148.4 °C
Freely Rotating Bonds: 2
Polar Surface Area: 16.13 Å2
Index of Refraction: 1.636
Molar Refractivity: 58.44 cm3
Molar Volume: 162.8 cm3
Polarizability: 23.16 ×10-24cm3
Surface Tension: 49.7 dyne/cm
Enthalpy of Vaporization: 56.36 kJ/mol
Vapour Pressure: 0.000291 mmHg at 25°C
The chemical synonyms of 2-Benzylaminopyridine (6935-27-9) are Benzyl-pyridin-2-yl-amine ; Aurora ka-4160 ; Alpha-benzylaminopyridine ; 2-Benzylaminopyridine ; n-Benzyl-2-pyridylamine ; n-Benzylpyridin-2-amine ; n-(2-pyridyl)Benzylamine ; n-(Phenylmethyl)-2-pyridinamine .Product categories of 2-Benzylaminopyridine (6935-27-9) are Pyridines derivates ; C9 to C46 ; Heterocyclic Building Blocks and Pyridines .The molecular structure of 2-Benzylaminopyridine (6935-27-9) is
.
2-benzylaminopyridine Uses
It can be used as pharmaceutical intermediate.
2-benzylaminopyridine Safety Profile
Hazard Codes: .gif)
Xn,Xi
Xn: Harmful
Xi: Irritant
Risk Statements: 22-37/38-41-40-36/37/38-20/21/22
22: Harmful if swallowed
40: Limited evidence of a carcinogenic effect
41: Risk of serious damage to eyes
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
37/38: Irritating to respiratory system and skin
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements; 26-39-36-22
22: Do not breathe dust
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
39: Wear eye/face protection
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