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Cas Database |
| Name |
3-(Trifluoromethyl)cinnamaldehyde |
EINECS | 1312995-182-4 |
| CAS No. | 262268-58-6 | Density | 1.241 g/cm3 |
| PSA | 17.07000 | LogP | 2.91750 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C10H7F3O | Boiling Point | 256.865 °C at 760 mmHg |
| Molecular Weight | 200.16 | Flash Point | 107.119 °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
(2E)-3-[3-(Trifluoromethyl)phenyl]prop-2-enal; |
Article Data | 17 |
3-(Trifluoromethyl)cinnamaldehyde Synthetic route
- 454-89-7
3-Trifluoromethylbenzaldehyde
- 75-07-0
acetaldehyde
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20 - 25℃; for 48h; Reagent/catalyst; Solvent; | 75% |
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With methyl trifluoromethanesulfonate In 2,2,2-trifluoroethanol at 70℃; for 1h; | 68% |
| With toluene-4-sulfonic acid In 1,2-dichloro-ethane at 60℃; for 5h; Meyer-Schuster Rearrangement; stereoselective reaction; | 50% |
- 454-89-7
3-Trifluoromethylbenzaldehyde
- 62942-43-2
formylmethyltriphenylphosphonium chloride
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at 20℃; for 48h; | 30% |
A
- 585-50-2
3-(3-trifluoromethylphenyl)propanoic acid
B
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With edetate disodium; thiamine diphosphate; sodium citrate; magnesium chloride In water; acetonitrile at 20℃; Rate constant; pH 6.0, brewers' yeast pyruvate decarboxylase (PDC, EC 4.1.1.1), also in the presence of pyruvamide; |
- 113048-69-4
(E)-3-(3-trifluoromethylphenyl)prop-2-en-1-ol
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With manganese(IV) oxide In dichloromethane at 20℃; for 2h; Oxidation; | |
| With dipyridinium dichromate In N,N-dimethyl-formamide at 20℃; for 1.5h; | |
| With manganese(IV) oxide In hexane; ethyl acetate at 20℃; Inert atmosphere; |
- 3054-95-3
acrylaldehyde diethyl acetal
- 401-81-0
m-trifluoromethylphenyl iodide
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| Stage #1: acrylaldehyde diethyl acetal; m-trifluoromethylphenyl iodide With potassium chloride; tetrabutylammonium acetate; palladium diacetate; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 2h; Heck Reaction; Stage #2: With hydrogenchloride In water |
- 454-89-7
3-Trifluoromethylbenzaldehyde
- 2136-75-6
(triphenylphosphoranylidene)acetaldehyde
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| With hydrogenchloride In N,N-dimethyl-formamide at 20℃; for 0.166667h; | |
| With hydrogenchloride In water at 20℃; for 3h; Product distribution / selectivity; |
- 3054-95-3
acrylaldehyde diethyl acetal
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| Stage #1: acrylaldehyde diethyl acetal; 3-F3CC6H4-Hal With potassium chloride; tetrabutylammonium acetate; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 1.5h; Stage #2: With hydrogenchloride at 20℃; for 0.166667h; |
- 401-78-5
3-bromo-1-trifluoromethylbenzene
- 262268-58-6
(E)-3-(3-(trifluoromethyl)phenyl)acrylaldehyde
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: n-Bu4NOAc; K2CO3; KCl / Pd(OAc)2 / dimethylformamide / 2 h / 90 °C 2: aq. HCl / dimethylformamide / 0.17 h / 20 °C View Scheme |
3-(Trifluoromethyl)cinnamaldehyde Chemical Properties
Empirical Formula: C10H7F3O
Molecular Weight: 200.1572
Nominal Mass: 200 Da
Average Mass: 200.1572 Da
Monoisotopic Mass: 200.044899 Da
Index of Refraction: 1.499
Molar Refractivity: 47.309 cm3
Molar Volume: 161.238 cm3
Surface Tension: 29.673 dyne/cm
Density: 1.241 g/cm3
Flash Point: 107.119 °C
Enthalpy of Vaporization: 49.44 kJ/mol
Boiling Point: 256.865 °C at 760 mmHg
Vapour Pressure: 0.015 mmHg at 25 °C
Structure of 3-(trifluoromethyl) Cinnamaldehyde (CAS NO.262268-58-6):
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Product Category of 3-(trifluoromethyl) Cinnamaldehyde (CAS NO.262268-58-6): Aromatic Cinnamic Acids, Esters and Derivatives
3-(Trifluoromethyl)cinnamaldehyde Specification
3-(trifluoromethyl) Cinnamaldehyde , its cas register number is 262268-58-6. It also can be called (2E)-3-[3-(Trifluoromethyl)phenyl]acrylaldehyde ; 2-propenal, 3-[3-(trifluoromethyl)phenyl]-, (2E)- ; and 3-(3-(Trifluoromethyl)phenyl)acrylaldehyde .
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