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4-Nitrophenylhydrazine hydrochloride

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Name

4-Nitrophenylhydrazine hydrochloride

EINECS 211-273-2
CAS No. 636-99-7 Density N/A
PSA 83.87000 LogP 2.97890
Solubility N/A Melting Point 205-207°C
Formula C6H7N3O2.HCl Boiling Point 344 °C at 760 mmHg
Molecular Weight 189.601 Flash Point 161.8 °C
Transport Information 2811 Appearance Light Brown or yellow granular crystals
Safety 26-36/37/39 Risk Codes 20/21/22-36/37/38
Molecular Structure Molecular Structure of 636-99-7 (4-Nitrophenylhydrazine hydrochloride) Hazard Symbols IrritantXi
Synonyms

Hydrazine,(4-nitrophenyl)-, monohydrochloride (9CI);Hydrazine, (p-nitrophenyl)-,hydrochloride (6CI,8CI);4-Nitrophenylhydrazine monohydrochloride;p-Nitrophenylhydrazine hydrochloride;

Article Data 9

4-Nitrophenylhydrazine hydrochloride Specification

The Hydrazine,(4-nitrophenyl)-, hydrochloride (1:1), with the CAS registry number 636-99-7 and EINECS registry number 211-273-2, has the the systematic name of (4-nitrophenyl)hydrazinium chloride. It is a kind of pink to orange crystalline powder, and belongs to the following product categories: Amines; blocks; Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes; Phenylhydrazine. And the molecular formula of the chemical is C6H7N3O2.HCl.

The characteristics of Hydrazine,(4-nitrophenyl)-, hydrochloride (1:1) are as followings: (1)ACD/LogP: 1.45; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.44; (4)ACD/LogD (pH 7.4): 1.45; (5)ACD/BCF (pH 5.5): 7.34; (6)ACD/BCF (pH 7.4): 7.49; (7)ACD/KOC (pH 5.5): 144.14; (8)ACD/KOC (pH 7.4): 147.06; (9)#H bond acceptors: 5; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 49.06 Å2; (13)Flash Point: 161.8 °C; (14)Enthalpy of Vaporization: 58.79 kJ/mol; (15)Boiling Point: 344 °C at 760 mmHg; (16)Vapour Pressure: 6.79E-05 mmHg at 25°C.

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. What's more, it is also Harmful by inhalation, in contact with skin and if swallowed. Therefore, you had better take the following instructions: Do not breathe dust; Avoid contact with skin and eyes; Wear suitable protective clothing, gloves and eye/face protection; In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Uses of Hydrazine,(4-nitrophenyl)-, hydrochloride (1:1): It can react with 3,3-dichloro-propenal to produce N-(3,3-dichloro-allylidene)-N'-(4-nitro-phenyl)-hydrazine. This reaction will need reagent AcONa.3H2O, and the menstruum ethanol. The reaction time is 3 hours with temperature of 20°C, and the yield is about 87%.   

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [Cl-].[O-][N+](=O)c1ccc(cc1)[NH2+]N
(2)InChI: InChI=1/C6H7N3O2.ClH/c7-8-5-1-3-6(4-2-5)9(10)11;/h1-4,8H,7H2;1H
(3)InChIKey: ZWWXDCOPVYATOQ-UHFFFAOYAR

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