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Basic information

  • Name:
  • Benzoic acid,3,3'-[(3-carboxy-4-oxo-2,5-cyclohexadien-1-ylidene)methylene]bis[6-hydroxy-,ammonium salt (1:3)

  • Superlist Name:
  • Aluminon
  • CAS No.:
  • 569-58-4

  • Molecular Structure:
  • Formula:
  • C22H14O9.3H3N
  • Molecular Weight:
  • 473.44
  • Deleted CAS:
  • 144097-08-5,25329-64-0,929976-57-8
  • Synonyms:
  • 1,4-Cyclohexadiene-1-carboxylicacid, 3-[bis(3-carboxy-4-hydroxyphenyl)methylene]-6-oxo-, triammonium salt(7CI);Aluminon (6CI);Benzoic acid,5-[(3-carboxy-4-hydroxyphenyl)(3-carboxy-4-oxo-2,5-cyclohexadien-1-ylidene)methyl]-2-hydroxy-,triammonium salt (9CI);C.I. Mordant Violet 39, triammonium salt (8CI);Ammonium aurintricarboxylate;Aurintricarboxylic acid ammonium salt;Triammonium aurintricarboxylate;Triammonium dihydroxyfuchsonetricarboxylate;
  • EINECS:
  • 209-319-1
  • Melting Point:
  • 220-225 °C (dec.)(lit.)
  • Boiling Point:
  • 759.6 °C at 760 mmHg
  • Flash Point:
  • 427.1 °C
  • Solubility:
  • water: 800 g/L (20 °C)
  • Appearance:
  • dark red crystalline powder
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 36/37/38
  • Safety Description:
  • 26-36-37/39 Details

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Chemistry

IUPAC Name: Azane; 5-[(3-Carboxy-4-hydroxyphenyl)-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)methyl]-2-hydroxybenzoic acid
The MF of Aluminon (CAS NO.569-58-4) is C22H23N3O9.

             
The MW of Aluminon (CAS NO.569-58-4) is 473.43.
Synonyms of Aluminon (CAS NO.569-58-4): 1,4-Cyclohexadiene-1-carboxylic acid, 3-(bis(3-carboxy-4-hydroxyphenyl)methylene)-6-oxo-, triammonium salt ; Triammonium Salt ; Triammonium 5,5'-(3-carboxylato-4-oxocyclohexa-2,5-dienylidenemethylene)disalicylate
Product Categories: (Chelating Reagents);Chelating Reagents;Analytical Chemistry
Apperance: dark red crystalline powder
Stability: Stable
Flash Point: 427.1 °C
Boiling Point: 759.6 °C
Melting Point: 220-225 °C
Water Solubility: 800 g/L (20 ºC)
EINECS: 209-319-1 
Merck: 14,322

Uses

 Aluminon (CAS NO.569-58-4),the triammonium salt of aurin tricarboxylic acid, is a dye commonly used to detect the presence of the aluminium ion in an aqueous solution. In addition to its use in qualitative inorganic analysis, aluminon has applications in pharyngeal aerosols. It forms brilliantly colored lake pigments with aluminum, chromium, iron, and beryllium.

Production

 Aluminon is prepared by reacting sodium nitrite with salicylic acid, adding formaldehyde, then treating with ammonia.

Toxicity Data With Reference

1.    

dni-mus-ipr 211 µmol/kg

    VAAZA2    Virchows Archiv, Abteilung B: Zellpathologie, Cell Pathology. 23 (1977),137.
2.    

orl-rat LD50:9 g/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 32 (3)(1988),48.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Human reproductive effects by ingestion: changes in male fertility. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NH3 and NOx.Safety information of Aluminon (CAS NO.569-58-4):
Hazard Codes  IrritantXi
Risk Statements 
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
WGK Germany  2
RTECS  GU4800000
HS Code  29189090

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