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Cas Database

Name	CYCLOTETRAMETHYLENE TETRANITRAMINE	EINECS	220-260-0
CAS No.	2691-41-0	Density	1.95 g/cm³
PSA	196.24000	LogP	-0.35080
Solubility	Soluble in acetone in water	Melting Point	286ºC
Formula	C4H8 N8 O8	Boiling Point	906.1ºC
Molecular Weight	296.156	Flash Point	501.8ºC
Transport Information	N/A	Appearance	White crystalline solid.
Safety	A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279°C. When heated to decomposition it emits toxic fumes of NO_x. See also EXPLOSIVES, HIGH.	Risk Codes	11-23/24/25-36/37/38
Molecular Structure		Hazard Symbols	TF
Synonyms	1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane;beta-1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane;cyclotetramethylene-tetranitramine;cyclotetramethylenetetranitramine;HMX;octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine;octogen	Article Data	27

CYCLOTETRAMETHYLENE TETRANITRAMINE Synthetic route

: 41378-98-7
1,3,5,7-tetraacetyloctahydro-1,3,5,7-tetrazocine

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With phosphorus pentoxide at 5 - 75℃; for 0.25h; Concentration; Temperature; Time;	95%

: 5755-28-2
1‑nitroso‑3,5,7‑trinitro‑1,3,5,7‑tetraazacyclooctane

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With nitric acid In water at 0 - 20℃; for 0.5h;	95%
With nitric acid at 25℃; for 0.5h; Reagent/catalyst;	92.8%

: 50850-26-5
1,5-diacetyl-3,7-dinitro-1,3,5,7-tetraazacyclooctane

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With nitric acid at 20℃; for 1h; Concentration; Time;	90%
With PPA; nitric acid	77%
With nitric acid; phosphorus pentoxide at 50℃; for 0.833333h;

: 949-56-4
3,7-dinitro-1,3,5,7-tetraaza-bicyclo[3.3.1]nonane

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With ammonium nitrate; nitric acid; dinitrogen pentoxide at 40℃; for 0.019445h; Ionic liquid; Sonication;	87.4%
Stage #1: 3,7-dinitro-1,3,5,7-tetraaza-bicyclo[3.3.1]nonane With ammonium nitrate; nitric acid; triethylammonium toluene-p-sulfonate; dinitrogen pentoxide at 0 - 25℃; for 0.333333h; Stage #2: With water at 40 - 65℃; for 0.5h;	69%
With bismuth (III) nitrate pentahydrate; nitric acid In neat (no solvent) at 0℃; for 2h; Reagent/catalyst;	65%

: diammonium 1,3,5,7-tetraazabicyclo[3.3.1]nonane-3,7-disulfonate sulfate

A: 121-82-4
Hexahydro-1,3,5-trinitro-1,3,5-triazine

B: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With ammonium nitrate; nitric acid In acetic anhydride; acetic acid at 70℃; for 0.333333h;	A 70% B 30%

: 100-97-0
hexamethylenetetramine

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With ammonium nitrate; boron trifluoride diethyl etherate; nitric acid; acetic anhydride In acetic acid at 44℃; for 1.25h;	16.9%
With nitric acid; acetic anhydride; acetic acid

: 50-00-0
formaldehyd

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
With ammonium hydroxide

: 17036-58-7
3,7-dinitro-1,3,5,7-tetraaza-bicyclo[3.3.2]decane

: 7697-37-2
nitric acid

: 108-24-7
acetic anhydride

NO3: NO3

: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
at 25℃;

: 17036-58-7
3,7-dinitro-1,3,5,7-tetraaza-bicyclo[3.3.2]decane

: 7697-37-2
nitric acid

NO3: NO3

A: 121-82-4
Hexahydro-1,3,5-trinitro-1,3,5-triazine

B: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

Conditions

Conditions	Yield
at 70 - 75℃;

: 7697-37-2
nitric acid

: 5754-75-6
1-acetoxymethyl-3,5,7-trinitro-[1,3,5,7]tetrazocane

: 108-24-7
acetic anhydride

: 64-19-7
acetic acid

NO3: NO3

A: 121-82-4
Hexahydro-1,3,5-trinitro-1,3,5-triazine

B: 2691-41-0
octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

...Expand

CYCLOTETRAMETHYLENE TETRANITRAMINE Chemical Properties

IUPAC Name:1,3,5,7-tetranitro-1,3,5,7-tetrazocane
Molecular Formula:C₄H₈N₈O₈
Molecular Weight:296.20
Density:1.95 g/cm³
Melting Point:286°C
Boiling Point:906.1°C
Flash Point:501.8°C
Solubility:Soluble in acetone in water
Appearance:White crystalline solid
Cyclotetramethylene tetranitramine's(2691-41-0) Synonyms: OCTAHYDRO-1,3,5,7-TETRANITRO-1,3,5,7-TETRAZOCINE;OCTOGEN;TETRAMETHYLENE TETRANITRAMINE;1,3,5,7-TETRANITRO-1,3,5,7-TETRAAZACYCLOOCTANE;HOMOCYCLONITE;HMX;LABOTEST-BB LT00044465;Cyclotetramethylene tetranitramine
Cyclotetramethylene tetranitramine's(2691-41-0) Molecular Structure:

CYCLOTETRAMETHYLENE TETRANITRAMINE Uses

Cyclotetramethylene tetranitramine(2691-41-0) is used for explosives.

CYCLOTETRAMETHYLENE TETRANITRAMINE Toxicity Data With Reference

1.	orl-mus LD50:1500 mg/kg	GISAAA Gigiena i Sanitariya. 40 (11)(1975),17.
2.	ivn-dog LDLo:40 mg/kg	EATR** U.S. Army, Edgewood Arsenal Technical Report. (Aberdeen Proving Ground, MD 21010) EB-TR-73040 .
3.	orl-gpg LD50:300 mg/kg	GISAAA Gigiena i Sanitariya. 40 (11)(1975),17.
4.	ivn-gpg LD50:28 mg/kg	EATR** U.S. Army, Edgewood Arsenal Technical Report. (Aberdeen Proving Ground, MD 21010) EB-TR-73040 .

CYCLOTETRAMETHYLENE TETRANITRAMINE Consensus Reports

Reported in EPA TSCA Inventory.

CYCLOTETRAMETHYLENE TETRANITRAMINE Safety Profile

A poison by ingestion and intravenous routes. An explosive. Decomposes violently at 279°C. When heated to decomposition it emits toxic fumes of NO_x. See also EXPLOSIVES, HIGH.

Safety Information
Hazard Codes F,T
Risk Statements 11-23/24/25-36/37/38
Safety Statements 16-27-45
RIDADR 0226
HazardClass 1.1D

CYCLOTETRAMETHYLENE TETRANITRAMINE Standards and Recommendations

DOT Classification: Forbidden (dry or unphlegmatized); DOT Class: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D

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