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Chromic nitrate

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Chromic nitrate

EINECS 236-921-1
CAS No. 13548-38-4 Density 1.00 g/mL at 20oC
PSA 0.00000 LogP 0.00000
Solubility in water: 81 g/100 mL (20 °C) Melting Point 60oC
Formula Cr(NO3)3 Boiling Point > 100 °C (212 °F) (decomp.)
Molecular Weight 238.01 Flash Point N/A
Transport Information UN 2720 5.1/PG 3 Appearance blue-violet crystals
Safety 17-26-36 Risk Codes 8-36/38
Molecular Structure Molecular Structure of 13548-38-4 (Chromic nitrate) Hazard Symbols OxidizingO,IrritantXi
Synonyms

Chromiumnitrate (Cr(NO3)3) (6CI);Nitric acid, chromium(3+) salt (8CI,9CI);Chromicnitrate;Chromic trinitrate;Chromium trinitrate;Chromium(3+) nitrate;Chromium(3+) trinitrate;Chromium(III) nitrate;SP 8-4JL;

 

Chromic nitrate Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 49 , 1990,p. 49.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.

Chromic nitrate Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Cr)/m3
ACGIH TLV: TWA 0.5 mg(Cr)/m3; Not Classifiable as a Carcinogen
DOT Classification:  5.1; Label: Oxidizer

Chromic nitrate Specification

Chromic nitrate, with the CAS registry number 13548-38-4, has the IUPAC name Chromium(III) nitrate. It is a blue-violet crystals which is very soluble in water and soluble in acids, bases, alchol and acetone. This chemical is an inorganic compound with the formula Cr(NO3)3 that will decompose at 100 °C. This chemical is stable at room temperature, but may explode if heated. Chromic nitrate is incompatible with organic materials and reducing agents. Its EINECS registry number is 236-921-1. Aqueous solution is green when heated but turn to reddish violet when cooled down.

Preparation: Chromium trioxide is restored by cane sugar in the presence of hydrogen nitrate and then is filtered. The filtrate is evaporated and concentrated. Finally, you can gain the Chromic nitrate after cooling crystallization and centrifugal separation.

16 CrO3 + 48 HNO3 + 9 H2O + C12H22O11 → 16 Cr(NO3)3.9H2O + 35 H2O + [O] + CO2

Uses: Chromic nitrate is used in the production of alkali metal-free catalysts and in pickling. In addition, it is also used in manufacture of glass, for ceramic underglaze, corrosion inhibitor and mordant in printing.

When you are using Chromic nitrate, you should be veru cautious about it. The substance is oxidising and irritant. When you contact with combustible material may cause fire. It is irritating to eyes and skin. In addition, you should keep it away from combustible material. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, you need wear suitable protective clothing.

Descriptors computed from structure of Chromic nitrate:
(1)Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Cr+3]
(2)InChI: InChI=1S/Cr.3NO3/c;3*2-1(3)4/q+3;3*-1
(3)InChIKey: PHFQLYPOURZARY-UHFFFAOYSA-N

Toxicity of Chromic nitrate:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 110mg/kg (110mg/kg)   Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 20, Pg. 590, 1978.
mouse LD50 oral 2976mg/kg (2976mg/kg)   Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 20, Pg. 590, 1978.
mouse LD50 subcutaneous 3232mg/kg (3232mg/kg)   Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 20, Pg. 590, 1978.
rat LD50 oral 3250mg/kg (3250mg/kg)   Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 22, Pg. 291, 1980.

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