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Basic information

  • Name:
  • Chromic chloride hexahydrate

  • CAS No.:
  • 10060-12-5

  • Molecular Structure:
  • Formula:
  • CrCl3.6(H2O)
  • Molecular Weight:
  • 266.45
  • Synonyms:
  • Chromiumchloride (CrCl3), hexahydrate (8CI,9CI);Chromiumchloride hexahydrate;Chromium trichloride hexahydrate;Chromium(III) chloridehexahydrate;Hexaaquachromium chloride;Hexaaquachromium(III) chloride;Chromium(Ⅲ)chloride hexahydrate;Chromium chloride(CrCl3), hydrate (1:6);
  • EINECS:
  • 233-038-3
  • Density:
  • 1.76 g/cm3
  • Melting Point:
  • 83 °C
  • Boiling Point:
  • 100 °C at 760 mmHg
  • Appearance:
  • Green crystalline powder
  • Hazard Symbols:
  • HarmfulXn
  • Risk Codes:
  • 22-36/37/38
  • Safety Description:
  • 24/25 Details
  • Transport Information:
  • UN 3260

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Chemistry

Molecular Structure of Chromic chloride hexahydrate (CAS No.10060-12-5):

Molecular Formula: CrCl3.6(H2O)
Molecular Weight: 266.45
IUPAC Name: Trichlorochromium hexahydrate 
CAS No: 10060-12-5
EINECS: 233-038-3
H bond acceptors: 1
H bond donors: 2
Freely Rotating Bonds: 0
Enthalpy of Vaporization: 40.65 kJ/mol
Boiling Point: 100 °C at 760 mmHg
Vapour Pressure: 24.5 mmHg at 25°C
Appearance: Greenish-black to violet crystals
Stability: Stable, but may be air-sensitive. Hygroscopic. Incompatible with lithium, nitrogen, strong oxidizing agents
Classification Code: Mutation data;Reproductive Effect;Supplement [trace mineral]
Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Chromium

Uses

Chromic chloride hexahydrate (10060-12-5) has many uses,as flowing:
1. It can be used as mordant in Printing and dyeing industry .
2. It can be used in the production of other chromium salts in Chemical industry.
3. It is good for the manufacture of a variety of chromium-containing pigment in Paint industry.
4. It used for the manufacture of chromium-containing catalyst in Organic synthesis.

Production

4Na2Cr2O7+16H2SO4+C8H12O6→4Cr2(SO4)3+4Na2SO4+22H2O+6CO2
Cr2(SO4)3+3Na2CO3→Cr2(CO3)3+3Na2SO4
Cr2(CO3)3+6HCl→2CrCl3+3H2O+3CO2

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LDLo intravenous 374mg/kg (374mg/kg)   Archives Internationales de Pharmacodynamie et de Therapie. Vol. 62, Pg. 330, 1939.
mouse LD50 intraperitoneal 285mg/kg (285mg/kg)   Toxicology and Applied Pharmacology. Vol. 63, Pg. 461, 1982.
mouse LDLo intravenous 1602mg/kg (1602mg/kg)   Archives Internationales de Pharmacodynamie et de Therapie. Vol. 62, Pg. 330, 1939.
rabbit LDLo intravenous 576mg/kg (576mg/kg)   Archives Internationales de Pharmacodynamie et de Therapie. Vol. 62, Pg. 330, 1939.
rat LD50 oral 1790mg/kg (1790mg/kg)   Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice, Czechoslavakia, Mar. 29, 1977Vol. 29MAR1977

Safety Profile

Safety Information of Chromic chloride hexahydrate (CAS No.10060-12-5):
Hazard Codes: HarmfulXn
Risk Statements: 22-36/37/38
R22:Harmful if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25 
S24/25:Avoid contact with skin and eyes.
RIDADR: UN3260
WGK Germany: 1
RTECS: GB5450000
HazardClass: 8
PackingGroup: III

Specification

   Chromic chloride hexahydrate (CAS No.10060-12-5), it also can be called Chlorid chromity hexahydrat [Czech] ; Chromic chloride ; Chromic chloride in plastic container ; Chromium(III) chloride hexahydrate .

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