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Name	DI(2-ETHYLHEXYL) PEROXYDICARBONATE	EINECS	240-282-4
CAS No.	16111-62-9	Density	1.001 g/cm³
PSA	71.06000	LogP	5.64060
Solubility	insoluble in water	Melting Point	<-57oC
Formula	C18H34 O6	Boiling Point	382.1 °C at 760 mmHg
Molecular Weight	346.464	Flash Point	160.2 °C
Transport Information	UN 3113	Appearance	Colorless liquid, unpleasant odor
Safety		Risk Codes	R21; R23/25; R34; R43; R48/22
Molecular Structure		Hazard Symbols	T,C
Synonyms	Peroxydicarbonicacid, bis(2-ethylhexyl) ester (7CI,8CI,9CI); 2-Ethylhexyl peroxydicarbonate;223EN40; Bis(2-ethylhexyl) perdicarbonate; Bis(2-ethylhexyl) peroxydicarbonate;Bis(ethylhexyl) peroxydicarbonate; Di-2-ethylhexyl percarbonate;Di-2-ethylhexyl peroxydicarbonate; EHP; Espercarb 840M; Kayacarbon EH; Lup 223;Luperox 223; Luperox 223EN40; Luperox 223V75; Lupersol 223; Peroyl OPP; PeroylOPP 60E; Trigonox EHP; Trigonox EHP-C 75; Trigonox EHP-W 40	Article Data	4

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Synthetic route

: 24468-13-1
2-Ethylhexyl chloroformate

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

Conditions

Conditions	Yield
With dihydrogen peroxide In water at 30 - 35℃;	92%
With dihydrogen peroxide; sodium carbonate In water at 0 - 10℃; for 0.0618333h; Temperature; Reagent/catalyst; Flow reactor;	90.4%
With sodium hydroxide; water; dihydrogen peroxide

: 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 105-06-6
1,4-Divinylbenzene

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

: 2-(2-ethylhexyloxycarbonyloxy)-1-(2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 0 - 55℃; for 5h;	69.6%

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

: 115827-75-3
C9H17O3

Conditions

Conditions	Yield
at 20℃; Irradiation; laser flash photolysis (LFP);

5,5-Dimethyl-1-pyrroline N-oxide: 5,5-Dimethyl-1-pyrroline N-oxide

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

: C6H11NOCO3C8H17

Conditions

Conditions	Yield
In benzene at 26.84 - 59.84℃; Product distribution; Decomposition; addition;

: 24973-59-9
2,4,6-tri-tert-butyl-1-nitrosobenzene

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

: C6H5NO(C4H8)3C8H17CO3

Conditions

Conditions	Yield
In benzene at 79.84℃; Product distribution; Decomposition; addition;	51 % Spectr.

: 119391-92-3
N-[2H5]benzylidene-[2H9]tert-butylamine N-oxide

: 16111-62-9
di-(2-ethylhexyl)-peroxydicarbonate

: C4D9NOCHC6D5CO3C8H17

Conditions

Conditions	Yield
In benzene at 26.84 - 39.84℃; Product distribution; Decomposition; addition;

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Chemical Properties

DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9) appears colorless liquid, unpleasant odor.There are some properties.
Molecular Formula:C₁₈H₃₄O₆
Molecular Weight:346.459
EINECS:240-282-4
Density:1.001 g/cm³Boiling Point:382.1 °C at 760 mmHg
Flash Point:160.2 °C
Solubility:insoluble in water
liansport Information:UN 3113

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Uses

DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9) can be used as vinyl chloride polymerization initiator and ethylene polymerization initiator.

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Toxicity Data With Reference

orl-rat LD50:1020 mg/kg

BSPII* SPI Bulletin. (Society of the Plastics Industry, 250 Park Ave., New York, NY 10017) 1/75-19B .

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Consensus Reports

Reported in EPA TSCA Inventory.

DI(2-ETHYLHEXYL) PEROXYDICARBONATE Safety Profile

Moderately toxic by ingestion. When heated to decomposition DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9) emits acrid smoke and irritating fumes. See also PEROXIDES, ORGANIC.

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