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Basic Information
CAS No.: 16111-62-9
Name: Di-(2-ethylhexyl)peroxydicarbonate
Article Data: 4
Molecular Structure:
Molecular Structure of 16111-62-9 (Di-(2-ethylhexyl)peroxydicarbonate)
Formula: C18H34 O6
Molecular Weight: 346.464
Synonyms: Peroxydicarbonicacid, bis(2-ethylhexyl) ester (7CI,8CI,9CI); 2-Ethylhexyl peroxydicarbonate;223EN40; Bis(2-ethylhexyl) perdicarbonate; Bis(2-ethylhexyl) peroxydicarbonate;Bis(ethylhexyl) peroxydicarbonate; Di-2-ethylhexyl percarbonate;Di-2-ethylhexyl peroxydicarbonate; EHP; Espercarb 840M; Kayacarbon EH; Lup 223;Luperox 223; Luperox 223EN40; Luperox 223V75; Lupersol 223; Peroyl OPP; PeroylOPP 60E; Trigonox EHP; Trigonox EHP-C 75; Trigonox EHP-W 40
EINECS: 240-282-4
Density: 1.001 g/cm3
Melting Point: <-57oC
Boiling Point: 382.1 °C at 760 mmHg
Flash Point: 160.2 °C
Solubility: insoluble in water
Appearance: Colorless liquid, unpleasant odor
Hazard Symbols: T,C
Risk Codes: R21; R23/25; R34; R43; R48/22
Transport Information: UN 3113
PSA: 71.06000
LogP: 5.64060
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Synthetic route
24468-13-1

2-Ethylhexyl chloroformate

16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

Conditions
ConditionsYield
With dihydrogen peroxide In water at 30 - 35℃;92%
With dihydrogen peroxide; sodium carbonate In water at 0 - 10℃; for 0.0618333h; Temperature; Reagent/catalyst; Flow reactor;90.4%
With sodium hydroxide; water; dihydrogen peroxide
2564-83-2, 45842-10-2

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

105-06-6

1,4-Divinylbenzene

16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

2-(2-ethylhexyloxycarbonyloxy)-1-(2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions
ConditionsYield
at 0 - 55℃; for 5h;69.6%
...Expand
16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

115827-75-3

C9H17O3

Conditions
ConditionsYield
at 20℃; Irradiation; laser flash photolysis (LFP);
5,5-Dimethyl-1-pyrroline N-oxide

5,5-Dimethyl-1-pyrroline N-oxide

16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

C6H11NOCO3C8H17

Conditions
ConditionsYield
In benzene at 26.84 - 59.84℃; Product distribution; Decomposition; addition;
24973-59-9

2,4,6-tri-tert-butyl-1-nitrosobenzene

16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

C6H5NO(C4H8)3C8H17CO3

Conditions
ConditionsYield
In benzene at 79.84℃; Product distribution; Decomposition; addition;51 % Spectr.
119391-92-3

N-[2H5]benzylidene-[2H9]tert-butylamine N-oxide

16111-62-9

di-(2-ethylhexyl)-peroxydicarbonate

C4D9NOCHC6D5CO3C8H17

Conditions
ConditionsYield
In benzene at 26.84 - 39.84℃; Product distribution; Decomposition; addition;
Raw Materials
24468-13-1
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Chemistry

DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9) appears colorless liquid, unpleasant odor.There are some properties.
Molecular Formula:C18H34O6
Molecular Weight:346.459
EINECS:240-282-4
Density:1.001 g/cm3
Boiling Point:382.1 °C at 760 mmHg
Flash Point:160.2 °C
Solubility:insoluble in water
liansport Information:UN 3113

Uses

DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9) can be used as vinyl chloride polymerization initiator and ethylene polymerization initiator.

Toxicity Data With Reference

1.   

orl-rat LD50:1020 mg/kg

   BSPII*    SPI Bulletin. (Society of the Plastics Industry, 250 Park Ave., New York, NY 10017) 1/75-19B .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition DI(2-ETHYLHEXYL) PEROXYDICARBONATE(16111-62-9)  emits acrid smoke and irritating fumes. See also PEROXIDES, ORGANIC.