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Ethalfluralin

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Name

Ethalfluralin

EINECS 259-564-3
CAS No. 55283-68-6 Density 1.357 g/cm3
PSA 94.88000 LogP 4.97060
Solubility 0.2mg/L(25 oC) Melting Point 54 - 57oC
Formula C13H14 F3 N3 O4 Boiling Point 368.6 °C at 760 mmHg
Molecular Weight 333.267 Flash Point 176.7 °C
Transport Information UN 3077 Appearance N/A
Safety Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F and NOx. Risk Codes R50/53   
Molecular Structure Molecular Structure of 55283-68-6 (Ethalfluralin) Hazard Symbols
Synonyms

Benzenamine,N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-(trifluoromethyl)- (9CI);Buvilan; EL 161; Edge; Ethalfluralin; Sonalan

Article Data 5

Ethalfluralin Synthetic route

393-75-9

4-chloro-3,5-dinitrobenzotrifluoride

55283-68-6

ethalfluralin

Conditions
ConditionsYield
In water

Ethalfluralin Chemical Properties

Chemistry informtion about N-Ethyl-N-(2-Methyl-2-Propenyl)-2,6-Dinitro-4-(Trifluoromethyl)-Benzenamine (CAS NO.55283-68-6) is:
IUPAC Name: N-Ethyl-N-(2-Methylprop-2-Enyl)-2,6-Dinitro-4-(Trifluoromethyl)Aniline
Synonyms: Buvilan ; Ethafluralin ; N-Ethyl-N-(2-Methyl-2-Propenyl)-2,6-Dinitro-4-(Trifluoromethyl)-Benzenamin ; P-Toluidine,2,6-Dinitro-N-Ethyl-N-(2-Methyl-2-Propenyl)-Alpha,Alpha,Alpha-Trif ; Sonalan ; Sonalan(R) ; N-Ethyl-N-(2-Methyl-2-Propenyl)-2,6-Dinitro-4-(Trifluoromethyl)-Benzenamine ; N-Ethyl-N-(2-Methylallyl)-2,6-Dinitro-4-Trifluoromethyl-Aniline
Product Categories: Alpha sort ; DinitroanilinePesticides&Metabolites ; E-GAlphabetic ; DinitroanilineAlphabetic ; E ; EQ - EZ ; Herbicides ; Pesticides&Metabolites
MF: C13H14F3N3O4
MW: 333.26
EINECS: 259-564-3 
Density: 1.357 g/cm3
Flash Point: 176.7 °C
Boiling Point: 368.6 °C at 760 mmHg
Vapour Pressure: 1.26E-05 mmHg at 25°C 
Enthalpy of Vaporization: 61.52 kJ/mol 
Storage temp.: 0-6°C
Merck: 13,3754
Following is the molecular structure of N-Ethyl-N-(2-Methyl-2-Propenyl)-2,6-Dinitro-4-(Trifluoromethyl)-Benzenamine (CAS NO.55283-68-6) is:

Ethalfluralin Uses

 N-Ethyl-N-(2-Methyl-2-Propenyl)-2,6-Dinitro-4-(Trifluoromethyl)-Benzenamine (CAS NO.55283-68-6) is used as a Pre-emergent herbicide.

Ethalfluralin Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LD50 oral > 200mg/kg (200mg/kg)   Pesticide Manual. Vol. 9, Pg. 340, 1991.
dog LD50 oral > 200mg/kg (200mg/kg)   Pesticide Manual. Vol. 9, Pg. 340, 1991.
duck LD50 oral > 200mg/kg (200mg/kg)   Pesticide Manual. Vol. 9, Pg. 340, 1991.
mouse LD50 oral > 10gm/kg (10000mg/kg)   Analytical Methods for Pesticides and Plant Growth Regulators. Vol. 10, Pg. 341, 1978.
quail LD50 oral > 200mg/kg (200mg/kg)   Pesticide Manual. Vol. 9, Pg. 340, 1991.
rabbit LD50 skin > 2gm/kg (2000mg/kg)   Pesticide Manual. Vol. 9, Pg. 340, 1991.
rat LC50 inhalation 4980mg/m3/4H (4980mg/m3) behavioral: altered sleep time (including change in righting reflex) behavioral: somnolence (general depressed activity) behavioral: ataxia National Technical Information Service. Vol. OTS0543304,
rat LD50 oral 10gm/kg (10000mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 52, 1977.

 

Ethalfluralin Consensus Reports

Reported in EPA TSCA Inventory.

Ethalfluralin Safety Profile

Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F and NOx.
Hazard Codes:
DangerousN
Risk Statements:
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3077
RTECS: XU6200000

Ethalfluralin Specification

First Aid Measures:
Ingestion: Administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.
Inhalation: Move victim to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, pneumonitis or bronchits. Administer oxygen and assist ventilation as required.
Skin: Remove contaminated clothing and wash exposed area thoroughly with soap and water. Seek medical attention if irritation or pain persists. Personnel involved in washing patients should wear gloves and avoid contact with contaminated clothing.
Eyes: Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, tearing, or sensitivity to light persist, the patient should be seen in a health care facility.
Handling and Storage:
torage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

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