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Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester

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Name

Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester

EINECS 211-723-8
CAS No. 691-64-5 Density 1.007 g/cm3
PSA 52.60000 LogP 1.66980
Solubility N/A Melting Point 69-72 °C(lit.)
Formula C10H18O4 Boiling Point 229.3 °C at 760 mmHg
Molecular Weight 202.251 Flash Point 90 °C
Transport Information N/A Appearance N/A
Safety 26-36 Risk Codes 36/38
Molecular Structure Molecular Structure of 691-64-5 (DI-TERT-BUTYL OXALATE) Hazard Symbols IrritantXi
Synonyms

Ethanedioicacid, bis(1,1-dimethylethyl) ester (9CI);Oxalic acid, di-tert-butyl ester(7CI,8CI);Bis(1,1-dimethylethyl) oxalate;Di-tert-butyl oxalate;

Article Data 14

Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester Specification

The Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester, with the CAS registry number 691-64-5, is also known as Oxalic acid, di-tert-butyl ester(7CI,8CI). It belongs to the product categories of C10 to C11Alphabetic; Carbonyl Compounds; D; DIA - DIC; Esters. Its EINECS registry number is 211-723-8. This chemical's molecular formula is C10H18O4 and molecular weight is 202.2475. What's more, its IUPAC name is Ditert-butyl oxalate. 

Physical properties about Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester are: (1)ACD/LogP: 2.12; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.12; (4)ACD/LogD (pH 7.4): 2.12; (5)ACD/BCF (pH 5.5): 24.06; (6)ACD/BCF (pH 7.4): 24.06; (7)ACD/KOC (pH 5.5): 339.12; (8)ACD/KOC (pH 7.4): 339.12; (9)#H bond acceptors: 4; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 52.6 Å2; (13)Index of Refraction: 1.43; (14)Molar Refractivity: 51.85 cm3; (15)Molar Volume: 200.6 cm3; (16)Polarizability: 20.55×10-24 cm3; (17)Surface Tension: 30 dyne/cm; (18)Density: 1.007 g/cm3; (19)Flash Point: 90 °C; (20)Enthalpy of Vaporization: 46.59 kJ/mol; (21)Boiling Point: 229.3 °C at 760 mmHg; (22)Vapour Pressure: 0.07 mmHg at 25 °C.

Preparation of Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester: this chemical is prepared by 1,2-di-tert-butoxy-ethyne. This reaction needs reagent O3 and solvent CH2Cl2 at temperature of -110 °C. The reaction time is 5 min. The yield is 100 %. And the reaction equation is as followed:

Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester is prepared by 1,2-di-tert-butoxy-ethyne

Use of Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester: it is used to produce other chemicals. For example, it is used to produce Fluoro-oxalacetic acid di-tert-butyl ester. The reaction occurs with reagents potassium, t-butyl alcohol by heating for 3 hours. The yield is 83 %. And the reaction equation is as followed:

Ethanedioicacid, 1,2-bis(1,1-dimethylethyl) ester is used to produce Fluoro-oxalacetic acid di-tert-butyl ester

When you are dealing with this chemical, you should be very careful. This chemical is irritating to eyes and skin. Therefore, you should wear suitable protective clothing. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: O=C(OC(C)(C)C)C(=O)OC(C)(C)C
(2) InChI: InChI=1/C10H18O4/c1-9(2,3)13-7(11)8(12)14-10(4,5)6/h1-6H3
(3) InChIKey: CIYGMWIAXRMHQS-UHFFFAOYAM

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