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Cas Database |
| Name |
Ethyl hydroperoxide |
EINECS | N/A |
| CAS No. | 3031-74-1 | Density | 0.948g/cm3 |
| PSA | 29.46000 | LogP | 0.49590 |
| Solubility | N/A | Melting Point |
-100°C |
| Formula | C2H6 O2 | Boiling Point | 95°Cat760mmHg |
| Molecular Weight | 62.0684 | Flash Point | 11.3°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Explodes violently when superheated. The barium salt is heat- and impact-sensitive. Explosive reaction with hydroiodic acid or finely divided silver. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Ethylhydroperoxide (6CI,7CI,8CI); Ethyl hydrogen peroxide |
Article Data | 45 |
Ethyl hydroperoxide Synthetic route
- 74-84-0
ethane
A
- 79-21-0
peracetic acid
B
- 3031-73-0
methyl hydroperoxide
C
- 3031-74-1
ethyl hydroperoxide
D
- 15932-89-5
hydroxymethylhydroperoxide
| Conditions | Yield |
|---|---|
| With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.5h; Kinetics; Oxidation; Photolysis; | A 2% B 6.2% C 10.2% D 0.4% |
- 74-98-6
propane
A
- 79-21-0
peracetic acid
B
- 3031-73-0
methyl hydroperoxide
C
- 3031-74-1
ethyl hydroperoxide
D
- 15932-89-5
hydroxymethylhydroperoxide
| Conditions | Yield |
|---|---|
| With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.333333h; Kinetics; Oxidation; Photolysis; | A 0.1% B 3.39% C 0.61% D 0.14% |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide | |
| With dihydrogen peroxide | |
| With potassium hydroxide; dihydrogen peroxide man saeuert 10-stdg. Schuetteln mit Schwefelsaeure an und destilliert das zwischen 90grad und 100grad uebergegangene Destillat wird mit Kalilauge versetzt und im Vakuum konzentriert darauf saeuert man abermals an und destilliert ueber; | |
| With potassium hydroxide; dihydrogen peroxide In water Heating; |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide |
| Conditions | Yield |
|---|---|
| With oxygen at 25℃; Irradiation.mit UV-Licht <253.7 nm; Quecksilber-Sensibilisierung>; | |
| With AuPd; dihydrogen peroxide In water at 21℃; under 750.075 Torr; for 1h; |
| Conditions | Yield |
|---|---|
| With diethyl ether; oxygen at -75℃; |
| Conditions | Yield |
|---|---|
| With hydrogen; fluorine at -63.1 - 89.9℃; Rate constant; Irradiation; investigated by flash photolysis-time-resolved UV spectroscopy; |
- 74-84-0
ethane
A
- 67-56-1
methanol
B
- 50-00-0
formaldehyd
C
- 64-18-6
formic acid
D
- 74-85-1
ethene
E
- 3031-74-1
ethyl hydroperoxide
F
- 75-07-0
acetaldehyde
| Conditions | Yield |
|---|---|
| With nitrogen; oxygen; chlorine at 298℃; under 700 Torr; for 4h; Product distribution; Irradiation; |
- 821-14-7
azoethane
A
- 64-17-5
ethanol
B
- 3031-74-1
ethyl hydroperoxide
C
- 628-37-5
diethyl peroxide
D
- 124-38-9
carbon dioxide
E
- 201230-82-2
carbon monoxide
F
- 75-07-0
acetaldehyde
| Conditions | Yield |
|---|---|
| With nitrogen; oxygen at 298℃; under 700 Torr; for 0.416667h; Product distribution; Irradiation; |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide |
Ethyl hydroperoxide Chemical Properties
Molecular Structure of Ethyl hydroperoxide (CAS NO.3031-74-1):
IUPAC: Hydroperoxyethane
Molecular Formula:C2H6O2
Molecular Weight:62.0678
Density:0.948 g/cm3
Flash Point:11.3oC
Boiling Point:95oC at 760 mmHg
SMILES:O(O)CC
InChI:InChI=1/C2H6O2/c1-2-4-3/h3H,2H2,1H3
InChIKey:ILHIHKRJJMKBEE-UHFFFAOYAS
Index of Refraction:1.364
Molar Volume:65.4 cm3
Surface Tension:26.2 dyne/cm
Molar Refractivity:14.59 cm3
Enthalpy of Vaporization:39.01 kJ/mol
Vapour Pressure:27.4 mmHg at 25oC
Ethyl hydroperoxide Safety Profile
Explodes violently when superheated. The barium salt is heat- and impact-sensitive. Explosive reaction with hydroiodic acid or finely divided silver. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.
Ethyl hydroperoxide Standards and Recommendations
DOT Classification: Forbidden
Ethyl hydroperoxide Specification
Ethyl hydroperoxide with cas registry number of 3031-74-1 is also known as Hydroperoxide, ethyl ; Ethyl hydrogen peroxide . It is stable under normal temperatures and pressures but it also should be stored in a tightly closed container when not in use and stored in a cool, dry place. Ethyl hydroperoxide with cas registry number of 3031-74-1 is used as a pharmaceutical intermediate. It can be used to produce singlet molecular oxygen by decomposition.
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