2-METHYL-1-TRIDECENE

Base Information

• Chemical Name: 2-METHYL-1-TRIDECENE
• CAS No.: 18094-01-4
• Molecular Formula: C14H28
• Molecular Weight: 196.376
• Hs Code.: 2901299090
• Mol file: 18094-01-4.mol

Synonyms:2-Methyl-1-tridecene

Chemical Property of 2-METHYL-1-TRIDECENE

Chemical Property:

• Vapor Pressure: 0.037mmHg at 25°C
• Melting Point: -21.78°C
• Refractive Index: 1.4361
• Boiling Point: 249.1°C at 760 mmHg
• Flash Point: 99.8°C
• PSA: 0.00000
• Density: 0.771g/cm³
• LogP: 5.48340

Purity/Quality:

98% ^*data from raw suppliers

2-Methyltridec-1-ene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-METHYL-1-TRIDECENE

There total 17 articles about 2-METHYL-1-TRIDECENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2-bromoprop-1-ene (557-93-7) + lauric anhydride (645-66-9) → 2-methyl-1-tridecene (18094-01-4)

Guidance literature:

With pyridine N-oxide; [2,2]bipyridinyl; potassium fluoride; lithium chloride; nickel dichloride; zinc; In N,N-dimethyl acetamide; at 25 ℃; for 48h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.9b01048

Reference yield: 51.0%

2-methyl-2-tridecanol (32836-44-5) + diphenyl diselenide (1666-13-3) → 2-methyltridecane (1560-96-9) + 2-methyl-tridec-2-ene (62060-10-0) + 2-methyl-1-tridecene (18094-01-4) + (1,1-dimethyl-dodecylselanyl)-benzene

Guidance literature:

With lanthanum; chloro-trimethyl-silane; iodine; copper(l) iodide; In acetonitrile; at 82 ℃; for 1h;

DOI:10.1246/cl.2003.918

Reference yield: 51.0%

2-bromo-2-methyltridecane (1185727-02-9) → 2-methyl-tridec-2-ene (62060-10-0) + 2-methyl-1-tridecene (18094-01-4)

Guidance literature:

With [(dimethylphenylsilyl)methyl]magnesium chloride; 1,3-bis(mesityl)imidazolium chloride; cobalt(II) chloride; In tetrahydrofuran; 1,4-dioxane; at 50 ℃; for 1h; regioselective reaction; Inert atmosphere;

DOI:10.1021/ja804277x

upstream raw materials:

n-decyl magnesium bromide

3-Chloro-2-methylpropene

2-methyl-2-tridecanamine

methyllithium

Downstream raw materials:

2-methyltridecane

tridecan-2-one

2-methoxy-2-methyltridecan-1-ol

Refernces

• 1、 Chen, Hui,Sun, Shuhao,Liao, Xuebin. "Nickel-Catalyzed Decarboxylative Alkenylation of Anhydrides with Vinyl Triflates or Halides". supporting information. p. 3625 - 3630. Retrieved 2019/05/24.
• 2、 Kobayashi, Tsuneyuki,Ohmiya, Hirohisa,Yorimitsu, Hideki,Oshima, Koichiro. "Cobalt-catalyzed regioselective dehydrohalogenation of alkyl halides with dimethylphenylsilylmethylmagnesium chloride". supporting information; body text. p. 11276 - 11277. Retrieved 2009/02/05.