6-deoxy-1,2-O-(1-methylethylidene)hexofuranose

Base Information

• Chemical Name: 6-deoxy-1,2-O-(1-methylethylidene)hexofuranose
• CAS No.: 17668-66-5
• Molecular Formula: C9H16O5
• Molecular Weight: 204.2203
• Mol file: 17668-66-5.mol

Synonyms:

Chemical Property of 6-deoxy-1,2-O-(1-methylethylidene)hexofuranose

Chemical Property:

• Vapor Pressure: 8.43E-06mmHg at 25°C
• Boiling Point: 335.3°Cat760mmHg
• Flash Point: 156.6°C
• Density: 1.24g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6-deoxy-1,2-O-(1-methylethylidene)hexofuranose

There total 15 articles about 6-deoxy-1,2-O-(1-methylethylidene)hexofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-glucofuranoside (32785-99-2) → 6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose (17668-66-5)

Guidance literature:

With water; acetic acid; at 40 ℃; for 10h; regioselective reaction;

DOI:10.1002/ejoc.200801093

Reference yield: 92.0%

5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose (15354-69-5) → 6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose (17668-66-5)

Guidance literature:

With lithium aluminium tetrahydride;

Reference yield: 80.0%

6-deoxy-1,2-O-isopropylidene-6-(4'-methylbenzene)sulfonyloxy-D-glucofuranose (26275-20-7) → 6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose (17668-66-5)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 2h; Heating;

DOI:10.1016/S0040-4020(01)81641-0

upstream raw materials:

D-quionovose

acetone

3,5-Di-O-acetyl-1,2-O-isopropylidene-6-O-p-toluenesulfonyl-α-D-glucofuranose

5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose

Downstream raw materials:

O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-deoxy-α-D-glucofuranose

3,5-Di-O-benzoyl-6-desoxy-1,2-O-isopropyliden-α-D-glucofuranose

6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-glucofuranoside

1,2-Di-O-acetyl-3,5-di-O-benzoyl-6-desoxy-D-glucofuranose

Refernces

• 1、 Sartillo-Piscil, Fernando,Cruz, Silvano,Sánchez, Mario,H?pfl, Herbert,De Parrodi, Cecilia Anaya,Quintero, Leticia. "Conformational analysis of cyclic phosphates derived from 5-C′ substituted 1,2-O-isopropylidene-α-D-xylofuranose derivatives". . p. 4077 - 4083. Retrieved 2007/10/03.
• 2、 Hiebl, Johann,Zbiral, Erich. "Synthesis of Glycofuranosyl Formamides, Isocyanides, and Isocyanates Starting from the Corresponding Glycosyl Azides". . p. 765 - 774. Retrieved 2007/10/02.