Zirconiumfluoride

Base Information

• Chemical Name: Zirconiumfluoride
• CAS No.: 7783-64-4
• Molecular Formula: F₄Zr
• Molecular Weight: 167.218
• UNII: 1XHF39056H
• Nikkaji Number: J44.275E
• Mol file: 7783-64-4.mol

Synonyms:Zirconiumfluoride;zirconium(4+) tetrafluoride;ZIRCONIUM FLUORIDE [MI];AKOS015833208;A839228

Chemical Property of Zirconiumfluoride

Chemical Property:

• Appearance/Colour: white fine crystalline powder
• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 640 °C
• Refractive Index: 1.59
• Boiling Point: 905 °C
• PSA: 0.00000
• Density: 4,43 g/cm3
• LogP: 1.68080
• Water Solubility.: 1.388 g/100 mL
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 165.898311
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C,Xi
• Hazard Codes: C:Corrosive;;
• Statements: R34:; R36/37/38:
• Safety Statements: S26:; S27:; S28:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[F-].[Zr+4]

Technology Process of Zirconiumfluoride

There total 71 articles about Zirconiumfluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.5%

stannous fluoride + zirconium (7440-67-7) → tin (7440-31-5) + zirconium(IV) fluoride (851363-60-5,7783-64-4)

Guidance literature:

In melt; placing of mixt. of Zr with SnF2 (molar ratio SnF2:Zr=2.10) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.50 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;

Reference yield:

Cs5Zr4F21*3H2O → zirconium(IV) fluoride (851363-60-5,7783-64-4) + cesium hexafluorozirconate + cesium fluoride (13400-13-0)

Guidance literature:

In neat (no solvent); heating up to 505°C in air with rate of 8-10 K/min; cooling; monitoring by XRD;

DOI:10.1134/S0036023609040123

Reference yield:

zirconium silicide (12039-90-6) + fluorine (7782-41-4) → zirconium(IV) fluoride (851363-60-5,7783-64-4) + silicon tetrafluoride (7783-61-1)

Guidance literature:

In neat (no solvent); warming of ZrSi2 with F2 without inflammation;;

DOI:10.1007/BF01540839

upstream raw materials:

ziconium(IV) oxychloride octahydrate

fluorine

hydrogen fluoride

zirconium(IV) oxide

Downstream raw materials:

hydrogen fluoride

zirconium tetrahydroxide

zirconium(IV) oxide

lanthanum

Refernces

• 1、 El-Ghozzi, Malika,Avignant, Daniel,Guillot, Maurice. "". . p. 51 - 58. Retrieved 1994.
• 2、 Konings, R. J. M.,Hildenbrand, D. L.. "The vapor pressure, infrared spectrum, and thermodynamic properties of ZrF4(g)". . p. 155 - 164. Retrieved 1994.
• 3、 Coupe,Louer,Lucas,Leonard. "X-RAY SCATTERING STUDIES OF GLASSES IN THE SYSTEM ZrF4-BaF2.". . p. 523 - 529. Retrieved 1983.
• 4、 Rodriguez, V.,Couzi, M.,Tressaud, A.,Grannec, J.,Chaminade, J. P.,Soubeyroux, J. L.. "". . . Retrieved 1990.
• 5、 Kraus, Florian,Baer, Sebastian A.,Karttunen, Antti J.. "The complex amide K2[Zr(NH2)6]". . p. 1122 - 1130. Retrieved 2011.
• 6、 Kraus, Florian,Baer, Sebastian A.,Fichtl, Matthias B.. "The reactions of silver, zirconium, and hafnium fluorides with liquid ammonia: Syntheses and crystal structures of Ag(NH3) 2F·2NH3, [M(NH3)4F 4]·NH3 (M = Zr, Hf), and (N2 . p. 441 - 447. Retrieved 2009/04/13.