Potassium bisaccharate

Base Information

• Chemical Name: Potassium bisaccharate
• CAS No.: 576-42-1
• Molecular Formula: C6H10 O8 . K
• Molecular Weight: 248.231
• Hs Code.: 2918199090
• Mol file: 576-42-1.mol

Synonyms:D-Glucaricacid, monopotassium salt (9CI); Glucaric acid, monopotassium salt, D- (8CI);D-Saccharic acid monopotassium salt; Monopotassium D-glucarate; Potassium acidsaccharate; Potassium bisaccharate; Potassium hydrogen D-glucarate; Potassiumhydrogen saccharate

Chemical Property of Potassium bisaccharate

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 4.04E-27mmHg at 25°C
• Melting Point: 188oC (dec.)(lit.)
• Boiling Point: 766.4 °C at 760 mmHg
• Flash Point: 431.2 °C
• PSA: 158.35000
• Density: 1.939g/cm³
• LogP: -4.73550
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: DMSO (Slightly, Heated, Sonicated), Water (Slightly, Sonicated)

Purity/Quality:

99% ^*data from raw suppliers

D-Glucarate monopotassium ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: D-Glucarate Monopotassium is an intermediate in the synthesis of D-Glucaro-1,4-lactone Monohydrate (G415600), an anticancer agent. Chelating agent, rubber formulations, metal plating, soaps, and detergents.

Technology Process of Potassium bisaccharate

There total 15 articles about Potassium bisaccharate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

D-Glucose (2280-44-6) → D-glucaric acid monopotassium salt (576-42-1)

Guidance literature:

With potassium hydroxide; chlorine; potassium bromide; 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; In water; at 0 - 5 ℃; pH=11.4 - 11.7; Further Variations:; Reagents; Product distribution;

Reference yield: 70.0%

D-glucose (50-99-7) → C6H5O9(3-)*3K(1+) + C6H5O9(3-)*3K(1+) + D-glucaric acid monopotassium salt (576-42-1)

Guidance literature:

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium D-gluconate; potassium hydroxide; In water; at 5 ℃; pH=12.2; optical yield given as %de; Electrochemical reaction;

DOI:10.1016/j.carres.2010.12.017

Reference yield: 67.9%

→ D-saccharic acid potassium salt (576-42-1,18404-47-2,18404-62-1,36439-43-7,84864-60-8,84878-11-5)

Guidance literature:

upstream raw materials:

D-glucose

D-glucaric acid

D-saccharic acid potassium salt

D-Glucose

Downstream raw materials:

D-glucaramide

hexanedioic acid dimethyl ester

furan-2,5-dicarboxylic acid

catena{D-saccharatetriaquamagnesium}

Refernces

• 1、 Ibert, Mathias,Fuerts, Patrick,Merbouh, Nabyl,Feasson, Christian,Marsais, Francis. "Evidence of benzilic rearrangement during the electrochemical oxidation of D-glucose to D-glucaric acid". . p. 512 - 518. Retrieved 2011.
• 2、 -. "METHOD OF PREPARING D-GLUCARO-1,4:6,3-DILACTONE". Paragraph 0065-0067. . Retrieved 2020/03/09.
• 3、 -. "METHOD FOR PRODUCING ADIPAMIDE AS INTERMEDIATE FOR PRODUCTION OF RAW MATERIAL FOR BIO-BASED NYLON". Paragraph 0044-0053. . Retrieved 2020/03/17.