Zinc dibenzyldithiocarbamate

Base Information

• Chemical Name: Zinc dibenzyldithiocarbamate
• CAS No.: 14726-36-4
• Molecular Formula: C30H28N2S4Zn
• Molecular Weight: 610.22
• Hs Code.: 29302000
• Mol file: 14726-36-4.mol

Synonyms:Zinc,bis(dibenzyldithiocarbamato)- (7CI,8CI);Zinc,bis[bis(phenylmethyl)carbamodithioato-kS,kS']-, (T-4)- (9CI);(N,N-Dibenzyldithiocarbamato)zinc;Arazate;Bis(dibenzyldithiocarbamato)zinc;Nocceler ZTC;Rhenogran ZBEC70;Vulkacit ZBEC;ZBEC;

Chemical Property of Zinc dibenzyldithiocarbamate

Chemical Property:

• Appearance/Colour: white to off-white powder
• Vapor Pressure: 7.06E-07mmHg at 25°C
• Melting Point: 183-188 °C
• Boiling Point: 408.3 °C at 760 mmHg
• Flash Point: 200.8 °C
• PSA: 121.26000
• Density: ==
• LogP: 8.33990
• Solubility.: 44.7mg/L in organic solvents at 20 ℃
• Water Solubility.: 2.3μg/L at 20℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 608.042675
• Heavy Atom Count: 37
• Complexity: 531

Purity/Quality:

99% ^*data from raw suppliers

Zinc dibenzyldithiocarbamate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CN(CC2=CC=CC=C2)C(=S)[S-].C1=CC=C(C=C1)CN(CC2=CC=CC=C2)C(=S)[S-].[Zn+2]
• Uses: Dibenzyldithiocarbamic acid zinc salt is a useful analytical tool, used in the detection of copper in plant and biological tissues. It has also been used in the preparation of dithiocarbamate ligand for the stabilization of gold nanoparticles. Accelerator for latex dispersions and cements

Technology Process of Zinc dibenzyldithiocarbamate

There total 5 articles about Zinc dibenzyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.8%

carbon disulfide (75-15-0,12122-00-8) + zinc(II) oxide + dibenzylamine (103-49-1) → zinc dibenzyl dithiocarbamate (14726-36-4)

Guidance literature:

With RP-98; FMES; In water; for 6h; Reagent/catalyst; Reflux; Large scale;

Reference yield: 98.1%

carbon disulfide (75-15-0,12122-00-8) + zinc(II) oxide + dibenzylamine (103-49-1) → zinc dibenzyl dithiocarbamate (14726-36-4)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; at 25 ℃; for 6h; Temperature;

Reference yield: 78.5%

sodium dibenzyldithiocarbamate (55310-46-8) + zinc(II) chloride (7646-85-7,24359-56-6) → bis(N,N-dibenzyldithiocarbamato-S,S′)zinc(II) (14726-36-4)

Guidance literature:

In water; at 20 ℃; for 2h;

DOI:10.1080/00958972.2021.1887482

upstream raw materials:

carbon disulfide

dibenzylamine

sodium dibenzyldithiocarbamate

zinc(II) chloride

Downstream raw materials:

NbCl(OCH₃)2((C₆H₅CH₂)2NCS₂)2

bis(N,N-dibenzyldithiocarbamato-S,S′)copper(II)

Zn(S₂CN(CH₂Ph)2)2(phen)

Refernces

• 1、 Sathiyaraj,Thirumaran. "Structural, morphological and optical properties of iron sulfide, cobalt sulfide, copper sulfide, zinc sulfide and copper-iron sulfide nanoparticles synthesized from single source precursors". . . Retrieved 2020.
• 2、 -. "Rubber vulcanization accelerator dibenzyl di-thio amino a acid zinc preparation method". Paragraph 0023; 0024;. . Retrieved 2016/10/07.