Technology Process of C14H8(C6H5)2BC6H2(CH3)3
There total 5 articles about C14H8(C6H5)2BC6H2(CH3)3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium tert-butylate / Inert atmosphere
1.2: Inert atmosphere
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 °C / Inert atmosphere
2.3: -78 - 20 °C / Inert atmosphere
3.1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate / water; toluene / 16 h / Inert atmosphere; Reflux
4.1: boron tribromide / 48 h / 50 °C / Inert atmosphere; Sealed bomb
4.2: 16 h / Inert atmosphere
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; n-butyllithium; potassium tert-butylate; palladium diacetate; boron tribromide;
In
diethyl ether; hexane; water; toluene;
1.2: Wittig reaction / 3.1: Suzuki coupling;
DOI:10.1021/om2000597
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium tert-butylate / Inert atmosphere
1.2: Inert atmosphere
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 °C / Inert atmosphere
2.3: -78 - 20 °C / Inert atmosphere
3.1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate / water; toluene / 16 h / Inert atmosphere; Reflux
4.1: boron tribromide / 48 h / 50 °C / Inert atmosphere; Sealed bomb
4.2: 16 h / Inert atmosphere
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; n-butyllithium; potassium tert-butylate; palladium diacetate; boron tribromide;
In
diethyl ether; hexane; water; toluene;
1.2: Wittig reaction / 3.1: Suzuki coupling;
DOI:10.1021/om2000597
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C / Inert atmosphere
1.2: 2 h / -78 °C / Inert atmosphere
1.3: -78 - 20 °C / Inert atmosphere
2.1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate / water; toluene / 16 h / Inert atmosphere; Reflux
3.1: boron tribromide / 48 h / 50 °C / Inert atmosphere; Sealed bomb
3.2: 16 h / Inert atmosphere
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; n-butyllithium; palladium diacetate; boron tribromide;
In
diethyl ether; hexane; water; toluene;
2.1: Suzuki coupling;
DOI:10.1021/om2000597