((CH₃CH₂)2NO)2Ti(CH₂C₆H₅)2

Base Information

• Chemical Name: ((CH₃CH₂)2NO)2Ti(CH₂C₆H₅)2
• CAS No.: 677796-56-4
• Molecular Formula: C₂₂H₃₄N₂O₂Ti
• Molecular Weight: 406.404
• Mol file: 677796-56-4.mol

Synonyms:

Chemical Property of ((CH₃CH₂)2NO)2Ti(CH₂C₆H₅)2

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of ((CH₃CH₂)2NO)2Ti(CH₂C₆H₅)2

There total 1 articles about ((CH₃CH₂)2NO)2Ti(CH₂C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

N-ethyl-N-hydroxy-ethanamine (3710-84-7) + tetrabenzyl titanium (17520-19-3) → ((CH3CH2)2NO)2Ti(CH2C6H5)2 (677796-56-4)

Guidance literature:

In hexane; byproducts: toluene; (Schlenk or drybox); addn. of ligand to a soln. of titanium compd. in hexanes at -30°C, stirring for 6 h at room temp.; concn., cooling to -45°C, decantation, recrystn. (hexanes, -45°C); elem. anal.;

DOI:10.1021/om0305521

Reference yield:

((CH3CH2)2NO)2Ti(CH2C6H5)2 (677796-56-4) + tris(pentafluorophenyl)borate (1109-15-5) → ((CH3CH2)2NO)2TiCH2C6H5(1+)*C6H5CH2B(C6F5)3(1-)=((CH3CH2)2NO)2TiCH2C6H5C6H5CH2B(C6F5)3 (677796-59-7)

Guidance literature:

In benzene-d6; (Schlenk or drybox); addn. of a soln. of titanium complex in C6D6 to a soln. of boron compd. at room temp.; detected by NMR;

DOI:10.1021/om0305521

upstream raw materials:

N-ethyl-N-hydroxy-ethanamine

tetrabenzyl titanium

Downstream raw materials:

((CH₃CH₂)2NO)2TiCH₂C₆H₅⁽¹⁺⁾*C₆H₅CH₂B(C₆F₅)3^(1-)=((CH₃CH₂)2NO)2TiCH₂C₆H₅C₆H₅CH₂B(C₆F₅)3

Refernces