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CAS No.: | 118647-53-3 |
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Name: | 3-(Bromomethyl)phenylacetic acid |
Article Data: | 16 |
Molecular Structure: | |
Formula: | C9H9BrO2 |
Molecular Weight: | 229.073 |
Synonyms: | 3-BROMOMETHYLPHENYLACETIC ACID;3-bromomethyl carboxymethylbenzene; |
Density: | 1.565 |
Boiling Point: | 341℃ |
Flash Point: | 160℃ |
PSA: | 37.30000 |
LogP: | 2.20860 |
m-methylphenylacetic acid
(3-bromomethyl-phenyl)-acetic acid
Conditions | Yield |
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With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 16h; Reflux; Inert atmosphere; | 95% |
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 16h; Reflux; | 79.3% |
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 16h; Reflux; | 79.3% |
methanol
(3-bromomethyl-phenyl)-acetic acid
3-methoxymethylphenylacetic acid
Conditions | Yield |
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With sodium methylate Inert atmosphere; Reflux; | 99% |
(3-bromomethyl-phenyl)-acetic acid
2-(3-(bromomethyl)phenyl)ethanol
Conditions | Yield |
---|---|
With borane-THF In tetrahydrofuran at 0 - 20℃; for 2h; | 94% |
With borane-THF In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere; | 94% |
With borane-THF In tetrahydrofuran at 0 - 20℃; for 13h; | 85% |
With borane-THF In tetrahydrofuran at 0 - 20℃; for 13h; | 71% |
With borane-THF at 0℃; | 66% |
sodium acetate
(3-bromomethyl-phenyl)-acetic acid
(3-acetoxymethyl-phenyl)-acetic acid methyl ester
Conditions | Yield |
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In DMA at 120℃; for 4h; Irradiation; | 93% |
(3-bromomethyl-phenyl)-acetic acid
triphenylphosphine
[3-(carboxymethyl)benzyl](triphenyl)phosphonium bromide
Conditions | Yield |
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In acetonitrile for 16h; Heating / reflux; | 92.4% |
methanol
(3-bromomethyl-phenyl)-acetic acid
methyl 2-(3-(bromomethyl)phenyl)acetate
Conditions | Yield |
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With thionyl chloride In toluene at 0℃; for 3h; | 72% |
With hydrogenchloride at 0℃; | |
With thionyl chloride In toluene at 0℃; |
(3-bromomethyl-phenyl)-acetic acid
2-(3-formylphenyl)acetic acid
Conditions | Yield |
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Stage #1: (3-bromomethyl-phenyl)-acetic acid With hexamethylenetetramine; water In ethanol for 4h; Reflux; Inert atmosphere; Stage #2: With hydrogenchloride In ethanol; water for 0.5h; Reflux; Inert atmosphere; | 72% |
Stage #1: (3-bromomethyl-phenyl)-acetic acid With hexamethylenetetramine In ethanol; water for 10h; Reflux; Stage #2: With hydrogenchloride In ethanol; water for 0.5h; Reflux; | 66% |
(3-bromomethyl-phenyl)-acetic acid
Conditions | Yield |
---|---|
With silver nitrate In acetonitrile at 20℃; for 48h; Darkness; | 70% |
(3-bromomethyl-phenyl)-acetic acid
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dimethyl sulfoxide at 20℃; | 45% |
(3-bromomethyl-phenyl)-acetic acid
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dimethyl sulfoxide; acetone at 20℃; | 42% |