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An inclusion complex with [Gd(DMF)8]3+ ions encapsulated in pockets of an anionic array of [{Cu6(CN)9}3-]￥ units; A cyanide-bridged Cu-Gd layer structure

An inclusion complex with [Gd(DMF)8]3+ ions encapsulated in pockets of an anionic array of [{Cu6(CN)9}3-]￥ units; A cyanide-bridged Cu-Gd layer structure. Liu, Shengming; Meyers, Edward A.; Shore, Sheldon G. (Department of Chemistry, Ohio State University, Columbus, OH 43210, USA). Angewandte Chemie, International Edition, 41(19), 3609-3611 (English) 2002 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: ACIEF5. ISSN: 1433-7851. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 The reaction of GdCl3 and pre-formed K[Cu(CN)2] in DMF leads to a lanthanide-transition metal complex with a layered structure, {Gd2(DMF)8Cu4(CN)10}￥. Treatment of GdCl3 with discrete quantities of CuCN and KCN, however, yields an inclusion complex with [Gd(DMF)8]3- ions located within pockets (see picture) throughout a three-dimensional array of [Cu6(CN)9]3- ions, {[Gd(DMF)8Cu6(CN)9].2DMF}￥. The crystal structures of both complexes were detd. 488097-30-9 and 13682-73-0 are just another two chemicals used in this study. .

Low-dimensional Compounds Containing Cyano Groups

All Rights Reserved. Low-dimensional Compounds Containing Cyano Groups. XIII. Structural-spectral Correlation of Copper Dicyanoargentates. Triscikova, L'ubica; Potocnak, Ivan; Chomic, Jozef; Baran, Peter ( Department of Inorganic Chemistry, University of Zuerich, Zurich CH-8057, Switz.). Transition Metal Chemistry (Dordrecht, Netherlands), 31(4), 504-515 (English) 2006 Springer. CODEN: TMCHDN. ISSN: 0340-4285. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 The new mixed-valence mixed-metal complex Cu(py)6Cu2Ag2(CN)6 (py = pyridine) possesses a three-dimensional polymeric crystal structure. The Cu(I) atom is tetrahedrally coordinated by two nitrogen atoms of pyridine mols., by one nitrogen atom of the dicyanoargentate anion and by one carbon atom of the cyano group. Both the dicyanoargentate anion and the cyano group bridge the Cu(I) atom with neighboring Cu(II) atoms. These are hexacoordinated as an elongated tetragonal bipyramid. The equatorial plane is formed by two nitrogen atoms from two pyridine mols. and two nitrogen atoms from bridging cyano groups. Axial positions are occupied by nitrogen atoms of the bridging [Ag(CN)2]- anions. Correlation between structures of the title compd.There are some commonly used reagents with their cas registry numbers 922500-30-9 and 13682-73-0 in this article. and seven other dicyanoargentates with their IR spectra was studied. The coordination mode of [Ag(CN)2]- anions in compds. Cu8-xAgx(tn)3(CN)10 x = 0.25, Cu(3-Mepy)2Ag2(CN)4, Cu(py)2Ag2(CN)4 and Cu(py)4Ag2(CN)4 (tn is 1,3-diaminopropane, 3-Mepy is 3-methylpyridine) is predicted based on this correlation. .