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Basic Information
CAS No.: 13709-36-9
Name: XENON DIFLUORIDE
Article Data: 102
Molecular Structure:
Molecular Structure of 13709-36-9 (XENON DIFLUORIDE)
Formula: F2Xe
Molecular Weight: 169.287
Synonyms: Xenondifluoride; Xenon difluoride (XeF2); Xenon(II) fluoride
EINECS: 237-251-2
Density: 4.32 g/mL at 25 °C(lit.)
Melting Point: 129 °C(lit.)
Boiling Point: 114.35°C (estimate)
Flash Point: n/a
Solubility: Decomposes in water.
Appearance: white crystalline solid
Hazard Symbols: O,T+,T
Risk Codes: 8-25-26-34
PSA: 0.00000
LogP: 0.45960
Synthetic route

xenon

7782-41-4

fluorine

13709-36-9

xenon difluoride

Conditions
ConditionsYield
In neat (no solvent) Xe and F2 condensed into nickel can (-196°C), warmed (room temp., pressure 34 atm.), preheated electric furnace (400°C) placed around the nickel can (7 h, pressure 78 atm.), quenched to room temp. in water, cooled (-78°C); excess Xe condensed into a storage cylinder (-196°C), evapn. (through a cold trap, -78°C);99.3%
In gas react. temp. of 400°C, Xe:F2 about 2.0, Monel vessel with volume between 95 and 1200 ml; cooling down with H2O;;>95
Electric Arc; react. of F2 with an excess of Xe in an electrical discharge; sublimation in vac., discarding the leading fraction;
7637-07-2

boron trifluoride

xenon

silver fluoride

7782-41-4

fluorine

A

14104-20-2

silver tetrafluoroborate

B

13709-36-9

xenon difluoride

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); treatment AgF with BF3 in HF, pptn. of AgBF4, adnn. of F2, removal of volatiles, addn. of Hf, BF3 and xenon (condensed in reactor, -100°C), warming to 20°C with stirring (thermal cycling repeated 3-4 times, in 2 h); removal of volatile (vac., -45°C, 5 h), XeF2 (U trap, -78°C); x-ray photography;A n/a
B 66%

silver(II) fluoride

7637-07-2

boron trifluoride

xenon

A

14104-20-2

silver tetrafluoroborate

B

13709-36-9

xenon difluoride

Conditions
ConditionsYield
With HF In hydrogen fluoride HF (liquid); mixing of AgF2 and BF3 in HF (-100°C), warming(to room temp., stirring), addn. of xenon (stirring 12 h); removal of volatile (-45°C, vac.), XeF2 (U trap, -78°C); x-ray powder photography and Raman spectroscopy; novolatile AgBF4; x-ray powder photography;A n/a
B 57.9%
375-00-8

heptafluorobutyronitrile

21308-45-2

xenon difluoride * AsF5

A

13709-36-9

xenon difluoride

B

112144-32-8

n-C3F7CNXeF cation

Conditions
ConditionsYield
In further solvent(s) BrF5 as solvent, equimolar amts., low temp.,;
21308-45-2

xenon difluoride * AsF5

353-85-5

trifluoroacetonitrile

A

13709-36-9

xenon difluoride

B

119127-09-2

CF3CNXeF(1+)

Conditions
ConditionsYield
In further solvent(s) BrF5 as solvent, equimolar amts., low temp.,;
21308-45-2

xenon difluoride * AsF5

422-04-8

pentafluoropropionitrile

A

13709-36-9

xenon difluoride

B

112144-30-6

C2F5CNXeF(1+)

Conditions
ConditionsYield
In further solvent(s) BrF5 as solvent, equimolar amts., low temp.,;
10578-16-2

dinitrogen difluoride

xenon

A

13709-36-9

xenon difluoride

13709-61-0

xenon tetrafluoride

Conditions
ConditionsYield
With oxygen fluorides on fluorination of Xe by oxygen fluoride;; XeF4 is polluted with XeF2;;
on react. of Xe with excess N2F2 (N2F2 : Xe = 2:1) in Monel vessels (24h/90-100°C);;
With oxygen fluorides

xenon

A

13709-36-9

xenon difluoride

B

silver(II) fluoride

Conditions
ConditionsYield
In further solvent(s) solvent: anhydrous HF; AgF3 in solvent exposed to large excess of Xe gas at 20 ° C, mixture allowed to ionteract at ca. 20 ° C for 1 h,; tube cooled to -78 ° C,excess Xe and solvent removed under vac.,mixture warmed to ca. 20 ° C,XeF2 on the walls of the tube and AgF2 in the bottom (X-ray powder photograph identical with that of authentic sample);
373-91-1

hypofluorous acid trifluoromethyl ester

13709-36-9

xenon difluoride

Conditions
ConditionsYield
byproducts: CF3OOCF3; on heating;;
byproducts: CF3OOCF3; on heating;;
7783-41-7

difluoroether

xenon

13709-36-9

xenon difluoride

Conditions
ConditionsYield
on exposure of OF2-Xe (1:1) mixtures;;
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     China (Mainland)  |  Contact Details

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     China (Mainland)  |  Contact Details

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     China (Mainland)  |  Contact Details

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    WLP Ingredient Inc was formerly known as Green Valley Biochemical, which was founded in Hong Kong in 2013 and WLPI was officially registered in 2019. In 2023, it reached a long-term strategic cooperation agreement with a local factory of plant extrac

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