Detail of "15573-38-3"

Reference

(Cyanomethyl)phosphines from trimethylsilylphosphines

(Cyanomethyl)phosphines from trimethylsilylphosphines. Dahl, Otto (H. C. Oersted Inst., Univ. Copenhagen, Copenhagen, Den.). Acta Chem. Scand., Ser. B, B30(8), 799-800 (English) 1976. CODEN: ACBOCV. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Ph2PCH2CN was prepd. 15573-38-3 is also in the experiment. in 71% yield by treating Ph2PSiMe3 with ClCH2CN. PhP(CH2CN)2 was similarly obtained in 50% yield from PhP(SiMe3)2 and P(CH2CN)3 in 10% yield from P(SiMe3)3. Oxidn. of PhP(CH2CN)2 with NO2 gave 70% PhP(O)(CH2CN)2. P(CH2CN)3 similarly gave 90% P(O)(CH2CN)3 with H2O2. .

Supercritical fluid-liquid-solid synthesis of gallium phosphide nanowires

Some chemicals with cas registry numbers like 7440-57-5 and 15573-38-3 are also used. Supercritical fluid-liquid-solid synthesis of gallium phosphide nanowires. Davidson, Forrest M., III; Wiacek, Robert; Korgel, Brian A. (Department of Chemical Engineering, Center for Nano- and Molecular Science and Technology and Texas Materials Institute, University of Texas at Austin, Austin, TX 78712, USA). Chemistry of Materials, 17(2), 230-233 (English) 2005 American Chemical Society. CODEN: CMATEX. ISSN: 0897-4756. DOCUMENT TYPE: Journal CA Section: 75 (Crystallography and Liquid Crystals) A method is presented for the prepn. of GaP nanowires called supercrit. fluid-liq.-solid (SFLS) growth. The GaP nanowires were synthesized in hexane at 500° and 37 MPa starting from (tBu)3Ga and P(SiMe3)3 in the presence of dodecanethiol-stabilized Au nanocrystals. The microstructure and compn. of the samples were characterized by XRD, HRSEM, EDS, and HRTEM. The role of the Au nanocrystal dispersion during the prepn. was investigated by varying the synthesis conditions. The Au nanocrystals serve as the primary metal seeds and are necessary to produce high-quality nanowires with const. diams. .