Products Categories
CAS No.: | 2114-39-8 | ||||||||
---|---|---|---|---|---|---|---|---|---|
Name: | 2-BROMO-1-PHENYLPROPANE | ||||||||
Article Data: | 38 | ||||||||
Molecular Structure: | |||||||||
Formula: | C9H11 Br | ||||||||
Molecular Weight: | 199.09 | ||||||||
Synonyms: | (2-Bromopropyl)benzene;(?à)-2-Bromo-1-phenylpropane;1-Bromo-1-methyl-2-phenylethane; 1-Phenyl-2-bromopropane;2-Bromo-1-phenylpropane | ||||||||
Density: | 1.307g/cm3 | ||||||||
Melting Point: | -10°C (estimate) | ||||||||
Boiling Point: | 228°Cat760mmHg | ||||||||
Flash Point: | 90.6°C | ||||||||
Appearance: | clear colorless to light brown liquid | ||||||||
Hazard Symbols: | |||||||||
Risk Codes: | 36/37/38 | ||||||||
Safety: |
|
||||||||
PSA: | 0.00000 | ||||||||
LogP: | 3.01250 |
1-phenyl-2-propyl 2-(methoxyethoxyethylcarboxy)-1-benzosulfonate
(2-bromopropyl)-benzene
Conditions | Yield |
---|---|
With lithium bromide In acetone for 2h; | 96% |
With lithium bromide In acetone for 2h; Product distribution / selectivity; Heating / reflux; | 96% |
With sodium bromide In acetone for 30h; Product distribution / selectivity; Heating / reflux; | 11% |
(±)-1-phenylpropanyl-2-yl methansulfonate
(2-bromopropyl)-benzene
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolim bromide at 60℃; for 8h; Concentration; Temperature; Time; Inert atmosphere; Green chemistry; | 95% |
(±)-1-phenylpropanyl-2-yl methansulfonate
A
1-phenylpropene
B
(2-bromopropyl)-benzene
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolim bromide at 90℃; for 1h; Concentration; Temperature; Time; Inert atmosphere; Green chemistry; | A 34% B 95% |
Conditions | Yield |
---|---|
With carbon tetrabromide; N,N-dimethyl-formamide; sodium bromide; 4,7-diphenyl-2,1,3-benzothiadiazole In N,N-dimethyl-formamide at 20℃; for 24h; Schlenk technique; Irradiation; Green chemistry; | 88% |
With hydrogen bromide at 100℃; im Rohr; | |
With 3-ethyl-2-fluoro-benzothiazolium; tetrafluoroborate; lithium bromide In acetone | |
With pyridine; thionyl chloride; diethyl ether Erwaermen des Reaktionsprodukts mit Thionylbromid und wenig Pyridin-hydrobromid; | |
Multi-step reaction with 2 steps 1: pyridine / 20 °C 2: 1-n-butyl-3-methylimidazolim bromide / 8 h / 60 °C / Inert atmosphere; Green chemistry View Scheme |
Conditions | Yield |
---|---|
With C6H12N2O*BrH at 20℃; for 10h; | 82% |
With hydrogen bromide; acetic acid |
1-phenyl-2-propyl-4-toluenesulfonate
(2-bromopropyl)-benzene
Conditions | Yield |
---|---|
With lithium bromide In acetone for 11h; | 81% |
With lithium bromide In acetone for 11h; Product distribution / selectivity; Heating / reflux; | 81% |
With sodium bromide In acetone for 30h; Product distribution / selectivity; Heating / reflux; | 16% |
With lithium bromide In acetone |
Conditions | Yield |
---|---|
With aluminum oxide; zinc dibromide for 3h; Ambient temperature; | 77% |
With aluminum oxide; zinc dibromide at 15℃; for 1.5h; further catalysts and temperatures; | 68.3% |
allylbenzene
hydrogen bromide
acetic acid
(2-bromopropyl)-benzene
3-Phenyl-1-propanol
sulfuric acid
A
(2-bromopropyl)-benzene
B
1-Bromo-3-phenylpropane
1-phenyl-2-propyl-4-toluenesulfonate
(2-bromopropyl)-benzene
Conditions | Yield |
---|---|
With acetone |