Reference

Model Systems for Flavoenzyme Activity

Model Systems for Flavoenzyme Activity.Some chemicals with cas registry numbers like 368-77-4 and 19338-12-6 are also used. Regulation of Flavin Recognition via Modulation of Receptor Hydrogen Bond Donor-Acceptor Properties. Deans, Robert; Cook, Graeme; Rotello, Vincent M. (Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA). Journal of Organic Chemistry, 62(4), 836-839 (English) 1997 American Chemical Society. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 7 (Enzymes) We have synthesized a new family of receptors for flavins based on 6-aryl-2,4-(acyldiamino)-s-triazines. In these synthetic hosts, systematic variation of the spatially remote substituents on the 6-aryl ring alters the hydrogen-bond-donating abilities of the amide functionality and the hydrogen-bond-accepting properties of the triazine N(3). This variation results in a strong modulation of the efficiency of flavin binding, with assocn. consts. for the receptor flavin complexes ranging over an 8-fold range. .

Thin films by multilayer build-up of electron transport materials

Mruk, Ralf; Prehl, Sabine; Zentel, Rudolf (Institute of Organic Chemistry, University of Mainz, Mainz 55099, Germany). Macromolecular Rapid Communications, 24(17), 1014-1018 (English) 2003 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: MRCOE3. ISSN: 1022-1336. DOCUMENT TYPE: Journal CA Section: 38 (Plastics Fabrication and Uses) Section cross-reference(s): 35 We present the synthesis and the electrochem. characterization of polymeric electron transport materials, synthesized by polycondensation of substituted triazines and a,w-dihaloalkanes (e.g., 1,6-dibromohexane-2,4-di-(4-pyridyl)-6-((3-trifluoromethyl)phenyl)-1,3,5- triazine copolymer). They can be reversibly reduced with the least neg. potential at -0. 652131-64-1 and 368-77-4 are also in the experiment.39 V, which is below the redn. potential of oxygen. In addn., the formation of polyelectrolyte multilayers is possible by the electrostatic self-assembly method. This multilayer formation takes place in a very defined way up to thirty double layers. .