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CAS No.: | 469-38-5 |
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Name: | CYCLOARTENOL |
Article Data: | 11 |
Molecular Structure: | |
Formula: | C30H50O |
Molecular Weight: | 426.726 |
Synonyms: | 9,19-Cyclo-9b-lanost-24-en-3b-ol (8CI);Cycloartenol (6CI);9,19-Cyclo-24-lanosten-3b-ol;Cycloart-24-en-3b-ol;Handianol;NSC 670193; |
Density: | 1.01 g/cm3 |
Melting Point: | 115~117℃ |
Boiling Point: | 505.464 °C at 760 mmHg |
Flash Point: | 221.931 °C |
Hazard Symbols: | Xi |
Safety: | 22-24/25 |
PSA: | 20.23000 |
LogP: | 8.16890 |
Cycloartenol
cycloartenol
Conditions | Yield |
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With potassium hydroxide In ethanol for 4h; Heating; | 94% |
Alkaline hydrolysis; |
Conditions | Yield |
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With potassium hydroxide In methanol Yield given; |
Arundinol
cycloartenol
Conditions | Yield |
---|---|
With sodium hydroxide for 4h; Heating; | 0.02 g |
Conditions | Yield |
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With CAS1Ile841Val mutant; YPG+heme rearrangement; cyclization; |
cycloartenol
Conditions | Yield |
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With potassium hydroxide |
cycloartenol
Conditions | Yield |
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With Arabidopsis thaliana cycloartenol synthase Ile481Gly; Triton X-100 In phosphate buffer for 24h; pH=6.4; Product distribution; Further Variations:; Reagents; Cyclization; Enzymatic reaction; | |
With Pisum sativum cycloartenol synthase I365L mutant Reagent/catalyst; |
Conditions | Yield |
---|---|
With cycloartenol synthase I481V mutant In phosphate buffer at 20℃; for 24h; pH=7.4; Product distribution; Further Variations:; Reagents; |
methanol
Cycloartenol
A
24-methylenecycloartanol
B
cycloartenol
Conditions | Yield |
---|---|
With sodium hydroxide; water In ethanol; isopropyl alcohol for 2h; Heating / reflux; |
Conditions | Yield |
---|---|
With Pisum sativum cycloartenol synthase G617A mutant | |
With Pisum sativum cycloartenol synthase Y118L mutant |
squalene 2,3(S)-oxide
cycloartenol
Conditions | Yield |
---|---|
With cycloartenol synthase from leaves of Paris polyphylla Reagent/catalyst; |
This chemical is called 9,19-Cyclolanost-24-en-3-ol, (3beta)-, and it can also be named as Cycloartenol. With the molecular formula of C30H50O, its molecular weight is 426.72. The CAS registry number of this chemical is 469-38-5. Additionally, its product category is Tri-Terpenoids.
Other characteristics of the 9,19-Cyclolanost-24-en-3-ol, (3beta)- can be summarised as followings: (1)ACD/LogP: 10.31; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 10.305; (4)ACD/LogD (pH 7.4): 10.305; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 9617628; (8)ACD/KOC (pH 7.4): 9617628; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 20.23 Å2; (13)Index of Refraction: 1.539; (14)Molar Refractivity: 131.892 cm3; (15)Molar Volume: 421.038 cm3; (16)Polarizability: 52.286×10-24cm3; (17)Surface Tension: 39.656 dyne/cm; (18)Density: 1.013 g/cm3; (19)Flash Point: 221.931 °C; (20)Enthalpy of Vaporization: 89.25 kJ/mol; (21)Boiling Point: 505.464 °C at 760 mmHg; (22)Vapour Pressure: 0 mmHg at 25°C.
Production method of this chemical: The 9,19-Cyclolanost-24-en-3-ol, (3beta)- could be obtained by the reactant of 3β-(4-hydroxy-3-methoxy-trans-cinnamoyloxy)-9β,19-cyclo-lanost-24-ene. This reaction needs the reagent of 10N aq. KOH, and the solvent of ethanol. The yield is 94 %. In addition, this reaction should be taken for 4 hours. The other condition is heating.
Uses of this chemical: The 9,19-Cyclolanost-24-en-3-ol, (3beta)- could react with acetic acid anhydride, and obtain the 3b-acetoxy-9b,19-cyclo-lanost-24-ene. This reaction needs the reagent of pyridine. The yield is 98 %. In addition, this reaction should be taken for 15 hours at the ambient temperature.
When you are using this chemical, please be cautious about it as the following: Do not breathe dust. Avoid contacting with skin and eyes.
You can still convert the following datas into molecular structure:
1.SMILES: C[C@H](CCC=C(C)C)[C@H]1CC[C@@]2([C@@]1(CC[C@]34[C@H]2CC[C@@H]5[C@]3(C4)CC[C@@H](C5(C)C)O)C)C
2.InChI: InChI=1/C30H50O/c1-20(2)9-8-10-21(3)22-13-15-28(7)24-12-11-23-26(4,5)25(31)14-16-29(23)19-30(24,29)18-17-27(22,28)6/h9,21-25,31H,8,10-19H2,1-7H3/t21-,22-,23+,24+,25+,27-,28+,29-,30+/m1/s1
3.InChIKey: ONQRKEUAIJMULO-YBXTVTTCBS