Detail of "5063-03-6"

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A convenient synthesis of high-loaded palladium(II) ROMP polymers

A convenient synthesis of high-loaded palladium(II) ROMP polymers. Braddock, D. 542-92-7 and 5063-03-6 are also occured in this study. Christopher; Chadwick, David; Lindner-Lopez, Eduard ( Department of Chemistry, Imperial College London, London SW7 2AZ, UK). Tetrahedron Letters, 45(49), 9021-9024 (English) 2004 Elsevier B.V. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Section cross-reference(s): 78 Bis[1-(5-norbornen-2-yl)butan-1,3-dionato]palladium(II) was conveniently prepd. from 5-acetoacetyl-2-norbornene and sodium tetrachloropalladate. The former could be subjected to ROMP to give a highly-loaded palladium(II) ROMP polymer with a palladium loading of 23% by wt. .

Synthesis and certain transformations of hydroxyl-containing acetylene derivatives of norbornene

Synthesis and certain transformations of hydroxyl-containing acetylene derivatives of norbornene. Khabibova, A. K.; Dadasheva, Ya. A.; Gido Yanez, C.; Karaev, S. F. (Azerb. Inst. Neft. Khim., Baku, USSR). Azerb. Khim. Zh., (5), 48-52 (Russian) 1983. CODEN: AZKZAU. ISSN: 0005-2531. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) Section cross-reference(s): 29 Grignard reaction of 5-acetyl-2-norbornene with RCYCMgBr (R = Ph, HOCH2) gave the corresponding title compds. (I) in 50-69% yield. I (R = CH2OH) reacted with CH2:CHOBu and R1Cl (R1 = MeOCH2, Me3Si) to give 41-52% I (R = CH2OCHMeOBu, CH2OR1; same R1), and with HgO-H2SO4 to give 28% nonbornenyltetrahydrofuranone II. 2-Norbornen-5-ylpropargylcarbinol (III; R2 = H) (IV) reacted with ClCH2OPr, Ac2O and CH2:CHCN to give 58-67% III (R2 = CH2OPr, Ac, CH2CH2CN, resp.). Pr2SiMeH added to I (R = Ph) and IV to give the corresponding enols in 65-69% yields. 5063-03-6 which is the cas registry number of one of substances is just one of reagents here. .