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CAS No.: | 5677-55-4 |
---|---|
Name: | ubiquinol-10 |
Article Data: | 7 |
Molecular Structure: | |
Formula: | C19H28O4 |
Molecular Weight: | 320.429 |
Synonyms: | U-50,488H methanesulfonate;TYRPHOSTIN 25;ubiquinol-2; |
Density: | 1.06g/cm3 |
Boiling Point: | 490°Cat760mmHg |
Flash Point: | 250.1°C |
PSA: | 58.92000 |
LogP: | 4.65860 |
4-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-2,3-dimethoxy-6-methyl-phenol
ubiquinone Q2
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In tetrachloromethane at -15℃; |
2-[(E)-3,7-dimethyl-2,6-octadienyl]-5,6-dimethoxy-3-methyl-1,4-benzoquinone
ubiquinone Q2
Conditions | Yield |
---|---|
With sodium disulfite In diethyl ether; water Ambient temperature; | |
With sodium hydroxide; ascorbic acid In ethanol at 50℃; | |
With sodium dithionite; water In methanol for 0.166667h; |
A
2,2'-dipyridyldisulphide
B
carbon dioxide
C
2-[(E)-3,7-dimethyl-2,6-octadienyl]-5,6-dimethoxy-3-methyl-1,4-benzoquinone
D
ubiquinone Q2
Conditions | Yield |
---|---|
In acetonitrile Product distribution; Further Variations:; Solvents; Reagents; Decomposition; Irradiation; |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: t-BuOK / tetrahydrofuran; dimethylformamide / 2 h / -25 °C 2: 12.64 g / 4 h / 100 °C / 6 Torr 3: aq. Na2S2)4 / acetone / 0.5 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: 73 percent / KOt-Bu / toluene; 2-methyl-propan-2-ol / 1 h / 0 °C 2: 99 percent / toluene / 1 h / Heating 3: Na2S2O4, H2O / methanol / 0.17 h View Scheme | |
Multi-step reaction with 3 steps 1: NaH / dimethylsulfoxide; tetrahydrofuran / Ambient temperature 2: 30percent KOH/MeOH / 0 °C 3: BF3*OEt2 / CCl4 / -15 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 99 percent / AcOH / 24 h / 20 °C 2: t-BuOK / tetrahydrofuran; dimethylformamide / 2 h / -25 °C 3: 12.64 g / 4 h / 100 °C / 6 Torr 4: aq. Na2S2)4 / acetone / 0.5 h / 20 °C View Scheme | |
Multi-step reaction with 4 steps 1: 99 percent / methanol 2: 73 percent / KOt-Bu / toluene; 2-methyl-propan-2-ol / 1 h / 0 °C 3: 99 percent / toluene / 1 h / Heating 4: Na2S2O4, H2O / methanol / 0.17 h View Scheme |
4,5-dimethoxy-2-methyltricyclo[6.2.1.02,7]undeca-4,9-diene-3,6-dione
ubiquinone Q2
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: t-BuOK / tetrahydrofuran; dimethylformamide / 2 h / -25 °C 2: 12.64 g / 4 h / 100 °C / 6 Torr 3: aq. Na2S2)4 / acetone / 0.5 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: 73 percent / KOt-Bu / toluene; 2-methyl-propan-2-ol / 1 h / 0 °C 2: 99 percent / toluene / 1 h / Heating 3: Na2S2O4, H2O / methanol / 0.17 h View Scheme |
4a-((E)-3,7-Dimethyl-octa-2,6-dienyl)-6,7-dimethoxy-8a-methyl-1,4,4a,8a-tetrahydro-1,4-methano-naphthalene-5,8-dione
ubiquinone Q2
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 12.64 g / 4 h / 100 °C / 6 Torr 2: aq. Na2S2)4 / acetone / 0.5 h / 20 °C View Scheme | |
Multi-step reaction with 2 steps 1: 99 percent / toluene / 1 h / Heating 2: Na2S2O4, H2O / methanol / 0.17 h View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: PBr3 / diethyl ether 2: NaH / dimethylsulfoxide; tetrahydrofuran / Ambient temperature 3: 30percent KOH/MeOH / 0 °C 4: BF3*OEt2 / CCl4 / -15 °C View Scheme |
ubiquinone Q2
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 30percent KOH/MeOH / 0 °C 2: BF3*OEt2 / CCl4 / -15 °C View Scheme |
ubiquinone Q2
2-[(E)-3,7-dimethyl-2,6-octadienyl]-5,6-dimethoxy-3-methyl-1,4-benzoquinone
Conditions | Yield |
---|---|
With manganese(IV) oxide In tetrachloromethane Yield given; |