Detail of "657408-07-6"

CAS Number:
657408-07-6
Name:
Phosphine,dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)-
Superlist Name:
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Molecular Structure:
Formula:
C₂₆H₃₅O₂P
Molecular Weight:
410.53
Synonyms:
(2,6-Dimethoxy-1,1'-biphenyl-2-yl)dicyclohexylphosphine;2-(Dicyclohexylphosphino)-2',6'-dimethoxy-1,1'-biphenyl;Dicyclohexyl(2',6'-dimethoxybiphenyl-2-yl)phosphine;S-Phos;
Melting Point:
164-166 °C
Boiling Point:
513.3 °C at 760 mmHg
Flash Point:
330.7 °C
Hazard Symbols:
Xn
Risk Codes:
40
Safety:
24/25-36/37 Details

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A facile, microwave-assisted, palladium-catalyzed arylation of acetone: All Rights Reserved. A facile, microwave-assisted, palladium-catalyzed arylation of acetone. Chobanian, Harry R.; Liu, Ping; Chioda, Marc D.; Guo, Yan; Lin, Linus S. (Department of Medicinal Chemistry, Merck Research Laboratories, Merck & Co., Inc., Rahway, NJ 07065, USA). Tetrahedron Letters, 48(7), 1213-1216 (English) 2007 Elsevier Ltd. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 21 (General Organic Chemistry) The authors report an expedient method for the heteroarylation of acetone under tin-free conditions. The coupling is performed using the com. 657408-07-6 is just another one chemical used in this study. available enol silane of acetone (2-trimethylsilyloxypropene) and a corresponding aryl bromide, chloride or triflate under microwave-assisted conditions, with tris(dibenzylideneacetone)dipalladium or palladium acetate and 2-(2',6'-dimethoxybiphenyl)dicyclohexylphosphine as the catalyst system. .