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6846-35-1

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Basic Information
CAS No.: 6846-35-1
Name: 5-Amino-3H-1,2,4-dithiazole-3-thione
Article Data: 27
Molecular Structure:
Molecular Structure of 6846-35-1 (5-Amino-3H-1,2,4-dithiazole-3-thione)
Formula: C2H2N2S3
Molecular Weight: 150.249
Synonyms: 5-Amino-3H-1,2,4-dithiazole-3-thione;Xanthahydrogen;1,2,4-Dithiazole-3-thione, 5-amino-;5-amino-1,2,4-dithiazole-3-thione;Xanthanohydrogen;4-27-00-06755 (Beilstein Handbook Reference);Isoperthiocyanic acid;3H-1,2, 4-Dithiazole-3-thione, 5-amino-;5-Imino-1,2,4-dithiazolidine-3-thione;1,2,4-Dithiazolidine-3-thione, 5-imino-;3H-1,2,4-Dithiazole-3-thione, 5-amino- (8CI)(9CI);3H-1,2,4-Dithiazole-3-thione,5-amino-;5-Imino-1,2, 4-dithiazolidine-3-thione;Xanthane hydride;5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE;
EINECS: 229-933-3
Density: 2 g/cm3
Melting Point: 201-203 °C
Boiling Point: 282 °C at 760 mmHg
Flash Point: 124.4 °C
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36/37/39
PSA: 127.48000
LogP: 2.09750
Related products
Synthetic route
S,S-dimethyl dithiocarbonate

S,S-dimethyl dithiocarbonate

17356-08-0

thiourea

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
Stage #1: S,S-dimethyl dithiocarbonate; thiourea With toluene-4-sulfonic acid In ethanol for 6h; Reflux;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In ethanol at 30 - 50℃; for 14h; Concentration;		95.4%
463-56-9

thiocyanic acid

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
With water
With water
1147550-11-5

ammonium thiocyanate

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
With hydrogenchloride In water for 6h;35%
With hydrogenchloride; water Reinigung ueber das Bariumsalz der Persulfocyansaeure;
With sulfuric acid

3,5-di(3,4,4-trifluoro-3-butenylthio)-1,2,4-thiadiazole

bis-potassium salt of 3,5 dimercapto 1,2,4-thiadiazole

A

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

B

3-(4-nitrophenylmethylthio)-5-(3,4,4-trifluoro-3-butenylthio)-1,2,4-thiadiazole

Conditions
ConditionsYield
In water
...Expand
463-56-9

thiocyanic acid

A

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

B

108-04-3

cyano-dithiocarbamic acid

Conditions
ConditionsYield
With water
With mineral acid
potassium-salt of/the/ trithioallophanic acid

potassium-salt of/the/ trithioallophanic acid

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
With acid aqueous solution; iron(III) chloride
74237-96-0

trithioallophanic acid

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
With sulfuric acid
333-20-0

potassium thioacyanate

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

Conditions
ConditionsYield
With sulfuric acid; water
3129-90-6

isothiocyanic acid

A

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

B

74-90-8

hydrogen cyanide

463-56-9

thiocyanic acid

7732-18-5

water

A

6846-35-1

5-amino-3H-1,2,4-dithiazole-3-thione

B

108-04-3

cyano-dithiocarbamic acid

C

74-90-8

hydrogen cyanide

...Expand
Raw Materials
333-20-0
7732-18-5
1858-25-9
71-43-2
20939-17-7
13250-46-9
463-56-9
3129-90-6
Downstream Products
124-38-9
6635-73-0
52208-13-6
74-90-8
102-08-9
108-04-3
7783-06-4
13604-44-9
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Chemistry

5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE(6846-35-1) is the chemical compound with the formula C2H2N2S3. Its molar weight is 150.25g/mol.
5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE(6846-35-1) is also named 3-AMINO-1,2,4-DTHIAZOLE-5-THIONE;5-AMINO-[1,2,4]DITHIAZOLE-3-THIONE;XANTHANE HYDRIDE;4-dithiazole-3-thione,5-amino-2;4-dithiazolidine-3-thione,5-imino-2;5-imino-1,2,4-dithiazolidine-3-thione;isoperthiocyanicacid;xanthahydrogen.
Melting Point: 201-203 oC 
Boiling Point: 2.00 oC
Density: 2.00
Flash Point: 124 oC
Index of Refraction: 1.986 
Molar Refractivity: 37.12 cm3 
Molar Volume: 74.9 cm3  
Surface Tension: 91 dyne/cm  
Enthalpy of Vaporization: 52.09 kJ/mol 
Vapour Pressure: 0.00344 mmHg at 25 oC
The chemical structure of 5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE(6846-35-1) is
.

Uses

5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE(6846-35-1) is mainly used as thiofide.

Toxicity Data With Reference

1.   

orl-rat LD50:3050 mg/kg

   GISAAA    Gigiena i Sanitariya. 49 (4)(1984),90.
2.   

orl-mus LD50:1200 mg/kg

   GISAAA    Gigiena i Sanitariya. 49 (4)(1984),90.
3.   

ivn-mus LD50:56 mg/kg

   CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00229 .

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. When heated to decomposition it emits very toxic fumes of NOx and SOx.
Hazard Codes: Xi
Risk Statements: 36/37/38
36/37/38:  Irritating to eyes, respiratory system and skin 
Safety Statements: 26-36/37/39
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
RTECS: JO6500000
Hazard Note: Irritant.

Specification

5-IMINO-1,2,4-DITHIAZOLIDINE-3-THIONE(6846-35-1) should be stored in the sealed container.