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CAS No.: | 871-58-9 |
---|---|
Name: | N-BUTYLXANTHIC ACID POTASSIUM SALT |
Article Data: | 23 |
Molecular Structure: | |
Formula: | C5H9KOS2 |
Molecular Weight: | 188.356 |
Synonyms: | Potassium O-n-butyl xanthate;Potassium butyl dithiocarbonate;Potassium butyl xanthate;Potassium butylxanthogenate;Carbonicacid, dithio-, O-butyl ester, potassium salt (8CI);Xanthic acid, butyl-, potassium salt(6CI);Butyl potassium xanthogenate;O-Butylpotassium dithiocarbonate;Potassium O-butyl dithiocarbonate;Potassium O-butylxanthate; |
EINECS: | 212-808-2 |
Melting Point: | 70 °C (decomp) |
Boiling Point: | 168.6 °C at 760 mmHg |
Flash Point: | 55.7 °C |
Appearance: | Slight yellow or kelly free pellet |
Risk Codes: | 20/21/22-36/38 |
Safety: | 20/21-36/37/39 |
PSA: | 66.62000 |
LogP: | 2.28550 |
Conditions | Yield |
---|---|
With potassium hydroxide at 20℃; for 4h; | 90% |
Stage #1: butan-1-ol With potassium hydroxide for 4h; Schlenk technique; Inert atmosphere; Stage #2: carbon disulfide Schlenk technique; Inert atmosphere; | 80.8% |
Stage #1: butan-1-ol With potassium hydroxide at 20℃; for 2h; Stage #2: carbon disulfide | 71.1% |
Conditions | Yield |
---|---|
at 80℃; | |
at 80℃; |
Conditions | Yield |
---|---|
With potassium hydroxide; acetone |
Conditions | Yield |
---|---|
With carbon disulfide; potassium hydroxide | |
With carbon disulfide |
Conditions | Yield |
---|---|
Aliquat 336 In water | 98% |
In acetone for 10h; Heating; |
Conditions | Yield |
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Aliquat 336 In water | 97% |
Sb(3+)*OC6H4CHNC6H4S(2-)*Cl(1-)=(OC6H4CHNC6H4S)SbCl
potassium butylxanthate
[OC6H4CHNC6H4S]Sb(S2COC4H9)
Conditions | Yield |
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In carbon disulfide; benzene byproducts: KCl; moisture free atmosphere; stirring (room temp., 3 h); filtration, solvent removal (reduced pressure, crystn.), standing overnight (refrigerator), drying (reduced pressure); elem. anal.; | 96% |
antimony(III) bis(diethyldithiocarbamate) chloride
potassium butylxanthate
antimony(III) bis(diethyldithiocarbamato)n-butyldithiocarbonate
Conditions | Yield |
---|---|
In carbon disulfide; benzene byproducts: KCl; (moisture-free conditions) to the soln. of Sb-compound in anhyd. C6H6/CS2 was added potassium dithiocarbonate-compound, the mixt. was stirred for 4 h at room temp.; filtered, the solvent was removed under reduced pressure, crystd. from CH2Cl2; elem. anal.; | 96% |
potassium butylxanthate
1,3-dichlorotetrabutyldistannoxane
Conditions | Yield |
---|---|
In carbon disulfide byproducts: KCl; distannoxane in CS2 added to a suspn. of xanthate in CS2, mixt. stirred at room temp. for 3 h; KCl filtered off, solvent evapd. under reduced pressure; elem. anal.; | 95.13% |
potassium butylxanthate
diphenyltin(IV) dichloride
(C6H5)2Sn(SCSOCH2CH2CH2CH3)2
Conditions | Yield |
---|---|
In carbon disulfide byproducts: KCl; to a suspn. of xanthate in CS2 diorganotin dichloride in CS2 is added, mixt. stirred at room temp. for 3 h; KCl filtered off, solvent removed under reduced pressure; elem. anal.; | 95.11% |
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Molecular Formula: C5H9KOS2
Molecular Weight: 188.35
EINECS: 212-808-2
Polar Surface Area: 80.12 Å2
Flash Point: 55.7 °C
Storage temp: Refrigerator
Enthalpy of Vaporization: 38.84 kJ/mol
Boiling Point: 168.6 °C at 760 mmHg
Vapour Pressure: 2.13 mmHg at 25°C
IUPAC Name: Potassium butoxymethanedithioate
Properties of Potassium butylxanthate (CAS NO.871-58-9):Yellow crystals from H2O. Sol in H2O.
Product Categories: Classes of Metal Compounds ; K (Potassium) Compounds (excluding simple potassium salts) ; Typical Metal Compounds
Synonyms of Potassium butylxanthate (CAS NO.871-58-9): N-butylxanthic acid potassium salt ; Potassium N-butylxanthate ; Potassium butyl xanthate ; Butylpotassiumxanthate ; Butylpotassiumxanthogentate ; Butylxanthicacid,potassiumsalt ; Butyl-xanthicacipotassiumsalt ; Butylxanthogenandraselny
Following is the molecular structure of Potassium butylxanthate (CAS NO.871-58-9):
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intravenous | 158mg/kg (158mg/kg) | Archives Internationales de Pharmacodynamie et de Therapie. Vol. 135, Pg. 330, 1962. | |
rat | LC50 | inhalation | 7690mg/m3/2H (7690mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 102, 1982. | |
rat | LD50 | oral | 456mg/kg (456mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 102, 1982. | |
rat | LD50 | unreported | 465mg/kg (465mg/kg) | "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1015, 1986. |
Poison by intravenous route. Moderately toxic by ingestion. Mildly toxic by inhalation. When heated to decomposition it emits toxic fumes of SOx and K2O.
Safety Information of Potassium butylxanthate (CAS NO.871-58-9):
RIDADR: 3342
RTECS: FG1223000
HazardClass: 4.2
PackingGroup: II