Detail of "902-04-5"

CAS Number:
902-04-5
Name:
5'-Guanylic acid,2'-deoxy-
Molecular Structure:
Formula:
C10H14 N5 O7 P
Molecular Weight:
347.22
Synonyms:
Guanosine,2'-deoxy-, 5'-(dihydrogen phosphate) (8CI); Guanosine, 2'-deoxy-, 5'-phosphate(6CI); Guanosine, 2'-deoxy-, phosphate (7CI); 2'-Deoxy-5'-GMP;2'-Deoxy-5'-guanylic acid; 2'-Deoxy-GMP; 2'-Deoxyguanosine 5'-monophosphate;2'-Deoxyguanosine 5'-phosphate; 2'-Deoxyguanylic acid; 2'-dGMP; Deoxy-GMP;Deoxyguanosine 5'-monophosphate; Deoxyguanosine 5'-phosphate; NSC 82626; dGMP
Density:
2.32g/cm³
Boiling Point:
844.2°Cat760mmHg
Flash Point:
464.4°C
Safety:
WGK Germany 3

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Identification of oligonucleotide fragments produced in a strand scission reaction of the d(C-G-C-G-C-G) duplex by bleomycin: Identification of oligonucleotide fragments produced in a strand scission reaction of the d(C-G-C-G-C-G) duplex by bleomycin. Uesugi, Seiichi; Shida, Toshio; Ikehara, Morio; Kobayashi, Yuji; Kyogoku, Yoshimasa (Fac. Pharm. Sci., Osaka Univ. 71-30-7 and 9060-10-0 are cas registry numbers. These chemicals are also mentioned in this article., Suita 565, Japan). Nucleic Acids Res., 12(3), 1581-92 (English) 1984. CODEN: NARHAD. ISSN: 0305-1048. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacology) Section cross-reference(s): 28 As a model of DNA strand scission by bleomycin B2 (I) [9060-10-0], d(C-G-C-G-C-G) [58927-26-7] was treated with I in the presence of Fe and H2O2. The degrdn. products were identified as cytosine [71-30-7], deoxyguanosine 5'-phosphate [902-04-5], d(C-Gp) 3'-terminal carboxymethyl ester (II) [89773-10-4], and d(C-G-C-Gp) 3'-terminal carboxymethyl ester [89764-22-7] by UV spectroscopy, 1H- and 31P-NMR spectroscopy, and paper electrophoresis. For comparison purposes, II was synthesized from the corresponding protected dinucleotide and glycolic acid [79-14-1]. Thus, cleavage of the C-3'-C-4' bond of the sugar residues by I was proven. .

The role of hydroxyl radicals in the degradation of DNA by ozone: The role of hydroxyl radicals in the degradation of DNA by ozone. Van der Zee, J.; Dubbelman, T. M. A. R.; Van Steveninck, J. (Dep. Med. Biochem., Sylvius Lab.There are some reagents with their cas registry numbers 1032-65-1 and 3352-57-6 are used in this study., Leiden 2300 RA, Neth.). Free Radical Res. Commun., 2(4-6), 279-84 (English) 1987. CODEN: FRRCEX. ISSN: 8755-0199. DOCUMENT TYPE: Journal CA Section: 4 (Toxicology) The degrdn. of the nucleotides dAMP [653-63-4], dGMP [902-04-5], dCMP [1032-65-1] and dTMP [365-07-1] and of calf thymus DNA by O3 was studied. In all cases both base and sugar moiety were degraded. Furthermore, strand breaks were induced in calf thymus DNA. Hydroxyl radicals were probably involved in the oxidn. of the base in dAMP and of the deoxyribose ring, but not in the degrdn. of the other bases. This indicates that O3-induced DNA damage proceeds both directly via O3 mols. and indirectly via hydroxyl radicals. .