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| CAS No.: | 959-52-4 |
|---|---|
| Name: | 1,3,5-Triacryloylhexahydro-1,3,5-triazine |
| Article Data: | 12 |
| Molecular Structure: | |
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| Formula: | C12H15 N3 O3 |
| Molecular Weight: | 249.269 |
| Synonyms: | 1,3,5-Triazine,hexahydro-1,3,5-tris(1-oxo-2-propenyl)- (9CI); s-Triazine, 1,3,5-triacryloylhexahydro-(6CI,7CI,8CI); 1,3,5-Triacryloyl-s-triazine;1,3,5-Triacryloylaminohexahydro-s-triazine;1,3,5-Triacryloylhexahydro-1,3,5-triazine;1,3,5-Triacryloylhexahydro-s-triazine; 1,3,5-Triacryloylhexahydrotriazine;1,3,5-Triacryloyltrimethylenetriamine;1,3,5-Tris(acryloyl)hexahydro-s-triazine; DU 801; Fixierer P; Fixing Agent P;Hexahydro-1,3,5-triacryloyl-s-triazine; Hexahydrotris(acryloyl)-s-triazine; NSC63839; NSC 8185; TAF; TAF (crosslinking agent);Tri(N-acryloyl)hexahydrotriazine; Triacrylformal;Triacryloylhexahydro-s-triazine; Triacryloylhexahydrotriazine;Triacryloylperhydrotriazine; Tris(N-acryloyl)hexahydrotriazine;Tris(acryloyl)hexahydro-s-triazine |
| EINECS: | 213-501-6 |
| Density: | 1.197 g/cm3 |
| Melting Point: | 156 °C (dec.)(lit.) |
| Boiling Point: | 579.6 °C at 760 mmHg |
| Flash Point: | 301 °C |
| Solubility: | Slightly soluble in water |
| Hazard Symbols: |
|
| Risk Codes: | R23/24/25;R34;R42/43 |
| Safety: | Poison by ingestion and skin contact routes. Mutation data reported. A severe eye irritant. When heated to decomposition it emits toxic vapors of NOx. |
| Transport Information: | UN 2928 |
| PSA: | 60.93000 |
| LogP: | -0.27000 |
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| Conditions | Yield |
|---|---|
| Stage #1: 1,3,5-Trioxan; acrylonitrile With sulfuric acid In chlorobenzene at 80℃; for 5h; Stage #2: With sodium hydroxide In chlorobenzene at 5 - 20℃; for 2h; | 95.1% |
| With sulfuric acid; hydroquinone In tetrachloromethane; water at 80℃; for 1h; effect of the ratio between the catalyst and water present in the system; | 91% |
| With sulfuric acid; hydroquinone In tetrachloromethane at 80℃; for 1h; | 91% |
| Conditions | Yield |
|---|---|
| Amberlyst 15 resin In chlorobenzene at 80℃; for 4h; | 95% |
| With sulfuric acid In chlorobenzene at 70℃; for 3h; Temperature; Solvent; | 88.2% |
| With sulfuric acid | |
| With sulfuric acid; acetic anhydride |
- 96-27-5
rac-3-sulfanylpropane-1,2-diol
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 1123041-92-8
1,1′,1″-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one)
| Conditions | Yield |
|---|---|
| With propylamine In methanol for 0.166667h; Michael type addition; | 96% |
| In methanol at 30℃; for 0.25h; | 79.7% |
| Stage #1: rac-3-sulfanylpropane-1,2-diol; 1,3,5-triacryloylhexahydro-s-triazine In methanol at 20℃; for 0.25h; Stage #2: With hexan-1-amine In methanol at 20℃; | 68% |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 60-24-2
2-hydroxyethanethiol
- 40549-57-3
1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-hydroxyethylthio)propan-1-one)
| Conditions | Yield |
|---|---|
| With propylamine In methanol | 96% |
| With propylamine In methanol for 0.166667h; Michael type addition; | 92% |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 60-23-1
Cysteamine
- 1123041-98-4
1,1',1"-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-aminoethylthio)propan-1-one)
| Conditions | Yield |
|---|---|
| In methanol for 0.166667h; Michael type addition; | 95% |
| In methanol at 23℃; for 0.166667h; |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 2365-48-2
Methyl thioglycolate
- 1123041-93-9
trimethyl 2,2',2''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)triacetate
| Conditions | Yield |
|---|---|
| With propylamine In methanol; chloroform for 0.166667h; Michael type addition; | 94% |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 147-93-3
Thiosalicylic acid
- 1123042-01-2
2,2',2''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)tribenzoic acid
| Conditions | Yield |
|---|---|
| Stage #1: Thiosalicylic acid With potassium hydrogencarbonate In methanol at 60℃; for 1h; Stage #2: 1,3,5-triacryloylhexahydro-s-triazine In methanol at 20℃; for 0.166667h; Michael type addition; | 90% |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 1123042-03-4
3,3',3''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)tris(2-aminopropanoic acid)
| Conditions | Yield |
|---|---|
| In methanol; water for 0.416667h; Michael type addition; | 88% |
- 33941-15-0
1-aza-18-crown-6
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
| Conditions | Yield |
|---|---|
| In methanol at 50℃; for 24h; | 85.7% |
- 959-52-4
1,3,5-triacryloylhexahydro-s-triazine
- 66943-05-3
1,4,7,10-tetraoxa-15-azacyclopentadecane
| Conditions | Yield |
|---|---|
| In methanol at 50℃; for 24h; | 84.9% |
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Chemistry
IUPAC Name: 1,3,5-Triacryloylhexahydro-1,3,5-triazine
The MF of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is C12H15N3O3.
The MW of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is 249.27.
Synonyms of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4): 1,3,5-Triacryloylhexahydro-s-triazine ; 1-(3,5-diacryloyl-1,3,5-triazinan-1-yl)-2-propen-1-one ; 1,1',1'-(1,3,5-Triazinane-1,3,5-triyl)tris(2-propen-1-one) ; 1,3,5-Triacryloyl-1,3,5-triazinane ; 2-Propen-1-one,1,1',1''-(1,3,5-triazine-1,3,5(2H,4H,6H)-triyl)tris- ; 1,3,5-Triacryloylhexahydro-1,3,5-triazine
Product Categories: Acrylic Monomers;Monomers;Polyfunctional Acrylics
Index of Refraction: 1.539
EINECS: 213-501-6
Density: 1.197 g/ml
Flash Point: 301 °C
Boiling Point: 579.6 °C
Melting Point: 156 °C
Uses
1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is used as environmentally-friendly light-curing coatings,the best cross-linking agent of light-curing coating performance.
Toxicity Data With Reference
| 1. | eye-rbt 500 µg SEV | TXCYAC Toxicology. 40 (1986),145. | ||
| 2. | mnt-mus-ipr 9300 µg/kg | TXCYAC Toxicology. 40 (1986),145. | ||
| 3. | cyt-ham:ovr 700 µg/L | TXCYAC Toxicology. 40 (1986),145. | ||
| 4. | orl-rat LD50:350 mg/kg | TXCYAC Toxicology. 40 (1986),145. | ||
| 5. | skn-rbt LD50:70 mg/kg | TXCYAC Toxicology. 40 (1986),145. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by ingestion and skin contact routes. Mutation data reported. A severe eye irritant. When heated to decomposition it emits toxic vapors of NOx.Safety information of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4):
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Risk Statements
23/24/25 Toxic by inhalation, in contact with skin and if swallowed
34 Causes burns
42/43 May cause sensitization by inhalation and skin contact
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 2928 6.1/PG 2
WGK Germany 3
RTECS XY9260000
HazardClass 4.2
PackingGroup II