1128-57-0Relevant articles and documents
Nucleophilic deoxyfluorination of catechols
Nemoto, Hiroyuki,Nishiyama, Tsuyoshi,Akai, Shuji
supporting information; experimental part, p. 2714 - 2717 (2011/06/28)
Nucleophilic deoxyfluorinaiton of one of the two hydroxyl groups of catechols has been developed via the Umpolung concept. This method was successively applied to naturally occurring catechols, such as catechins and dopamine, to produce novel fluorinated
Highly substituted Schiff base macrocycles via hexasubstituted benzene: a convenient double Duff formylation of catechol derivatives
Shopsowitz, Kevin E.,Edwards, David,Gallant, Amanda J.,MacLachlan, Mark J.
scheme or table, p. 8113 - 8119 (2009/12/09)
The synthesis of soluble, shape-persistent macrocycles is important for developing new materials. Double Duff formylation of 4,5-dialkylcatechol derivatives yields 3,6-diformyl-4,5-dialkylcatechols in moderate yields. These hexasubstituted aromatics are u
Chemistry of 2-Methoxy-2,5-cyclohexadienones. I. Photochemistry of 2-Methoxy-4,4-dimethyl-2,5-cyclohexadienone
Matoba, Katsuhide,Karibe, Norio,Yamazaki, Takao
, p. 3906 - 3911 (2007/10/02)
The title compound, 2-methoxy-4,4-dimethyl-2,5-cyclohexadienone (V), was prepared from 2-methoxy-4,4-dimethyl-2-cyclohexenone (VIa).A methanolic solution of V was irradiated with a 200 W mercury lamp at -3 deg C to give 2,2-dimethoxy-6,6-dimethylbicyclo3