114389-80-9Relevant articles and documents
Lewis Acid-Catalyzed Rearrangement of Fluoroalkylated Propargylic Alcohols: An Alternative Approach to β-Fluoroalkyl-α,β-enones
Ramasamy, Manickavasakam,Lin, Hui-Chang,Kuo, Sheng-Chu,Hsieh, Min-Tsang
supporting information, p. 356 - 360 (2019/02/12)
A practical Lewis acid-catalyzed Meyer-Schuster rearrangement of fluoroalkylated propargylic alcohols, leading to a series of β-fluoroalkyl-α,β-enones, is developed. The methodology reported herein features moderate to high yields and high stereoselectivi
THE SYNTHESIS OF UNSATURATED TRIFLUOROMETHYL KETONES BY REGIOSELECTIVE ORGANOCUPRATE ADDITION TO ACETYLENIC TRIFLUOROMETHYL KETONES
Linderman, Russel J.,Lonikar, Madhu S.
, p. 5271 - 5274 (2007/10/02)
Regiospecific and stereoselective synthesis of unsaturated trifluoromethyl ketones has been accomplished by the addition of higher order cyano cuprates to acetylenic trifluoromethyl ketones.
