116019-90-0

Basic information

• Product Name: 1-Propen-2-ol, 1,1,3,3,3-pentafluoro-, lithium salt (1:1)
• CAS NO: 116019-90-0
• Molecular Formula: C3 H F5 O . Li
• Molecular Weight: 153.965
• Mol File: 116019-90-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Propen-2-ol, 1,1,3,3,3-pentafluoro-, lithium salt (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propen-2-ol, 1,1,3,3,3-pentafluoro-, lithium salt (1:1)(116019-90-0)
• EPA Substance Registry System: 1-Propen-2-ol, 1,1,3,3,3-pentafluoro-, lithium salt (1:1)(116019-90-0)

Safety Data

• Hazardous Substances Data: 116019-90-0(Hazardous Substances Data)

Downstream Products

• 119333-88-9 N-(1-Difluoromethyl-2,2,2-trifluoro-1-hydroxy-ethyl)-benzamide 
• 116019-97-7 Acetic acid (Z)-2-fluoro-2-phenyl-1-trifluoromethyl-vinyl ester 
• 116019-96-6 Acetic acid (E)-2-fluoro-2-phenyl-1-trifluoromethyl-vinyl ester 
• 885121-37-9 2,6-dicyclohexyl-5,5-difluoro-4-trifluoromethyl-1,3-dioxan-4-ol 
• 119333-87-8 2-Benzyloxy-1,1,1,3,3-pentafluoro-propan-2-ol 
• 116020-02-1 1,1,1,3,3-Pentafluoro-4-phenyl-pentane-2,2,4-triol 
• 119333-93-6 Benzoic acid (Z)-2-fluoro-1-trifluoromethyl-vinyl ester 
• 53841-60-4 2-benzoyloxy-1,1,3,3,3-pentafluoropropene 
• 116019-99-9 Benzoic acid (Z)-2-fluoro-1-trifluoromethyl-but-1-enyl ester 
• 116019-98-8 Benzoic acid (E)-2-fluoro-1-trifluoromethyl-but-1-enyl ester 
• 116020-01-0 4-hydroxy-1,1,1,3,3-pentafluoro-4-phenylbutan-2-one hemiacetal 
• 119333-91-4 1,1,1,3,3-Pentafluoro-3-(1-hydroxy-cyclohexyl)-propane-2,2-diol 

Relevant articles and documents

Preparation of polyfluoroenolates

Polyfluoroenolates, R1 CX=CR2 OM (R1 is F or a perfluoroalkyl group, R2 is a perfluoroalkyl group, X is F, Cl or Br), are easily formed at good yields by dehydrohalogenation reaction of polyfluoroalcoholates, R1 CXY--CR2 HOM (Y is F, Cl or Br), with a strong base such as, e.g., an alkyl metal or an aryl metal. A typical example of the polyfluoroenolates is lithium pentafluoro-2-propenolate which is obtained from hexafluoro-2-propanolate. A polyfluoroenolate of the above general formula can be converted into another polyfluoroenolate having an alkyl or aryl group in place of the halogen X by reaction with an alkyl or aryl metal.