116625-75-3

Basic information

• Product Name: 1,3-Propanedione, 1-(2-chlorophenyl)-3-phenyl-
• CAS NO: 116625-75-3
• Molecular Formula: C15H11ClO2
• Molecular Weight: 258.704
• Mol File: 116625-75-3.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1,3-Propanedione, 1-(2-chlorophenyl)-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanedione, 1-(2-chlorophenyl)-3-phenyl-(116625-75-3)
• EPA Substance Registry System: 1,3-Propanedione, 1-(2-chlorophenyl)-3-phenyl-(116625-75-3)

Safety Data

• Hazardous Substances Data: 116625-75-3(Hazardous Substances Data)

Upstream product

• 610-96-8 methyl chlorobenzoate 
• 98-86-2 acetophenone 
• 2142-68-9 1-(2-chlorophenyl)ethanone 
• 98-88-4 benzoyl chloride 
• 93-58-3 benzoic acid methyl ester 
• 16619-64-0 1-(2-chlorophenyl)-3-phenyl-2-propyn-1-one 
• 932-90-1 Benzaldoxime 
• 93-89-0 benzoic acid ethyl ester 
• 89-98-5 2-chloro-benzaldehyde 
• 38895-97-5 1-benzoyl-1,2-dibromo-2-(o-chlorophenyl)-ethane 
• 3300-67-2 3-(2-chlorophenyl)-1-phenylpropenone 
• 35022-42-5 2-chlorobenzoyl cyanide 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 34082-45-6 1-(2-chlorophenyl)-2-phenylethane-1,2-dione 
• 1069133-34-1 (S)-3-(2-chlorophenyl)-3-hydroxy-1-phenylpropan-1-one 
• 872333-00-1 (R)-3-(2-chlorophenyl)-3-hydroxy-1-phenylpropan-1-one 
• 525-82-6 FLAVONE 
• 82145-69-5 1-(2'-chlorophenyl)-2,2-dimethyl-3-phenylpropane-1,3-dione 
• 65-85-0 benzoic acid 
• 118-91-2 ortho-chlorobenzoic acid 
• 116625-80-0 (2-Chloro-phenyl)-(2-phenyl-[1,8]naphthyridin-3-yl)-methanone 

Relevant articles and documents

Synthesis of 1,3-diketones by reaction of α-haloketones with acyl cynides promoted by samarium diiodide

α-Haloketones reacted with acyl cyanides to form 1,3-diketones in the presence of samarium diiodide. The reaction was assumed to proceed via a mechanism involving samarium enolates in situ from α-haloketones.

Metal-Free, DBU-Mediated, Microwave-Assisted Synthesis of Benzo[c]xanthones by Tandem Reactions of Alkynyl-1,3-diketones

A base-mediated, green, microwave-assisted efficient preparation of a diverse benzoxanthone library from variety of readily accessible γ-alkynyl 1,3-diketones is reported. The synthesis is based on tandem reactions involving intramolecular cyclization, propargyl-allenyl isomerization, and electrocyclization in one pot. Some of the benzoxanthones are also synthesized by the one-pot reaction of 1,3-diketone and alkynyl bromide under basic heating conditions. This transformation also results in the construction of one new C?C bond and one new C?O bond. (Figure presented.).

Ru-Catalyzed Chemo- and Enantioselective Hydrogenation of β-Diketones Assisted by the Neighboring Heteroatoms

A highly chemo- and enantioselective hydrogenation of β-diketones was achieved by using [Ru(benzene)(S)-SunPhosCl]Cl for consistency in THF. The neighboring heteroatoms played important roles in guaranteeing the reactivity and controlling the chemoselectivity. These results suggested a potential approach for the clean and facile synthesis of functionalized chiral β-hydroxy ketones, which could otherwise be prepared through much less step-economic transformations.