117783-11-6Relevant articles and documents
A Synthesis of acetamidines
Harjani, Jitendra R.,Liang, Chen,Jessop, Philip G.
experimental part, p. 1683 - 1691 (2011/05/12)
The condensation of primary amine with N,N-dimethylacetamide dimethyl acetal yields amixture of acetamidine and imidate ester. The product distribution in this reaction depends on the temperature, solvent, and structure of the primary amine. It is possible to suppress the formation of imidate ester by performing the reaction in the presence of excess dimethyl amine, yielding acetamidine as the exclusive product. For acetamidines that cannot be purified either by crystallization or distillation, this new method is necessary for the generation of pure acetamidines in good yields.
STUDIES ON CYCLOPHOSPHAZENES. II. SYNTHESIS AND CATALYTIC ACTIVITY OF NEW TYPES OF HEXA-SUBSTITUTED CYCLOPHOSPHAZENIC PODANDS
Podda, Gianni
, p. 397 - 400 (2007/10/02)
The reaction between hexakis(p-hydroxybenzyloxy)cyclophosphazene 3 and polyethylene glycol monoalkyl ether tosylate leads to the formation of new types of hexakiscyclophosphazenes.The properties of these derivatives, including their catalytic activity under phase-transfer conditions, have been investigated.