119873-74-4

Basic information

• Product Name: Silanol, dimethyl[(1E)-2-phenylethenyl]-
• CAS NO: 119873-74-4
• Molecular Formula: C10H14OSi
• Molecular Weight: 178.306
• Mol File: 119873-74-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silanol, dimethyl[(1E)-2-phenylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanol, dimethyl[(1E)-2-phenylethenyl]-(119873-74-4)
• EPA Substance Registry System: Silanol, dimethyl[(1E)-2-phenylethenyl]-(119873-74-4)

Safety Data

• Hazardous Substances Data: 119873-74-4(Hazardous Substances Data)

Upstream product

• 541-05-9 Hexamethylcyclotrisiloxane 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 2370-88-9 2,4,6,8-tetramethylcyclotetrasiloxane 
• 917-54-4 methyllithium 
• 536-74-3 phenylacetylene 
• 104891-66-9 β-styrylchloromethyldimethylsilane 
• 4843-72-5 (E)-2-phenylethenyllithium 
• 873-66-5 1-propenylbenzene 
• 75-36-5 acetyl chloride 
• 174279-17-5 (E)-β-<(2,6-dimethylphenyl)dimethylsilyl>styrene 
• 119873-75-5 (E)-dimethyl(2-phenylethenyl)silane 
• 119873-73-3 β-styryl-N-pyrrolidinylmethyldimethylsilane 

Downstream Products

• 119873-76-6 Dimethyl-(3-phenyl-oxiranyl)-silanol 
• 39806-16-1 ethyl (2E,4E)-5-phenyl-penta-2,4-dienoate 
• 886-65-7 1,4-diphenyl-1,3-butadiene 
• 53423-25-9 (E)-1-methyl-2-styryl-benzene 
• 20780-53-4 (R)-Styrene oxide 
• 20780-54-5 (S)-styrene oxide 
• 13830-40-5 2-Phenyl-cyclopropanol, opt.-inakt. 
• 67456-93-3 1,3-dimethyl-2-[(E)-2-phenyl-1-ethenyl]benzene 
• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 

Relevant articles and documents

Highly selective and practical hydrolytic oxidation of organosilanes to silanols catalyzed by a ruthenium complex [9]

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Highly selective oxidation of organosilanes to silanols with hydrogen peroxide catalyzed by a lacunary polyoxotungstate

Silanol synthesis: Divacant lacunary polyoxotungstate (nBu4N+)4[g- SiW10O34(H2O)2] (I) is an efficient homogeneous catalyst for highly selective oxidation of organosilanes to silanols with 30/60% aqueous H2O2. Various kinds of silanes 1 containing aryl, alkyl, alkenyl, alkynyl and alkoxy groups are chemoselectively converted into the corresponding silanols 2 in high yields with only one equivalent of aqueous H2O2 with respect to the substrate.

[RuCl2(p-cymene)]2 on carbon: An efficient, selective, reusable, and environmentally versatile heterogeneous catalyst

(Matrix Presented) A heterogeneous ruthenium catalyst, easily prepared by adsorption of [RuCl2(p-cymene)]2 on activated carbon, exhibited a highly efficient and selective catalytic activity in various environmentally attractive transformations such as aerobic oxidation, hydrolytic oxidation, and dehydration processes with excellent recyclability.