1252763-55-5

Basic information

• Product Name: 10-benzyloxycarbonyl-9,10-dihydroacridine
• Synonyms: 10-benzyloxycarbonyl-9,10-dihydroacridine
• CAS NO: 1252763-55-5
• Molecular Weight: 315.371
• Mol File: 1252763-55-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 10-benzyloxycarbonyl-9,10-dihydroacridine(CAS DataBase Reference)
• NIST Chemistry Reference: 10-benzyloxycarbonyl-9,10-dihydroacridine(1252763-55-5)
• EPA Substance Registry System: 10-benzyloxycarbonyl-9,10-dihydroacridine(1252763-55-5)

Safety Data

• Hazardous Substances Data: 1252763-55-5(Hazardous Substances Data)

Upstream product

• 578-95-0 10H-acridin-9-one 
• 6630-33-7 ortho-bromobenzaldehyde 
• 583-53-9 2,3-dibromobenzene 
• 123335-02-4 bis-(2-bromophenyl)methanol 
• 621-84-1 O-benzyl carbamate 
• 61592-89-0 2,2’-dibromodiphenylmethane 
• 118-91-2 ortho-chlorobenzoic acid 
• 62-53-3 aniline 
• 91-40-7 2-(phenylamino)benzoic acid 
• 92-81-9 acridine 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 1252763-59-9 rac-10-benzyloxycarbonyl-9-(1'-oxocyclopent-2'-yl)acridane 
• 1370524-13-2 10-benzyloxycarbonyl-9-(2'-oxopropyl)-9,10-dihydroacridine 
• 1370524-14-3 rac-10-benzyloxycarbonyl-9-(1'-phenyl-2'-oxopropyl)-9,10-dihydroacridine 

Relevant articles and documents

Direct C(sp3)–H Sulfonylation of Xanthene Derivatives with Sodium Sulfinates by Oxidative Copper Catalysis

By employing a readily available CuCl/DDQ catalyst system, we herein report a direct C(sp3)–H sulfonylation of xanthene derivates with odorless sodium sulfinates. Various 9H-xanthenes, thioxanthenes, and 9,10-dihydroacridines are efficiently transformed into the desired benzylic sulfonyl products via a radical/radical cross-coupling process, proceeding with the merits of broad substrate scope, operational simplicity, good functional group compatibility, and mild reaction conditions.

Sulfonic acid-catalyzed autoxidative carbon-carbon coupling reaction under elevated partial pressure of oxygen

An aerobic organocatalytic oxidative C-C bond formation reaction of benzylic C-H bonds with various C-nucleophiles is described. The coupling reaction proceeds by simply stirring the substrates under elevated partial pressure of oxygen in the presence of a sulfonic acid catalyst at room temperature. Elevation of the pressure enables the reaction of a broad scope of nucleophile substrates otherwise showing poor reactivity at ambient pressure. The benzylic C-H bonds of xanthene, acridanes, isochromane and related heterocycles could be functionalized with nucleophiles including ketones, 1,3-dicarbonyl compounds and aldehydes. Electron-rich arenes could be utilized as nucleophiles at elevated temperatures. The reactions are believed to proceed via autoxidation of the benzylic C-H bonds to the hydroperoxides and subsequent nucleophilic substitution catalyzed by sulfonic acids. Copyright