1309595-83-2

Basic information

• Product Name: (4R,9S,10S,12R,E)-15-(benzyloxy)-10,12-bis((tert-butyldimethylsilyl)oxy)-4-((triethylsilyl)oxy)-6,9-dimethylpentadec-6-en-8-one
• Synonyms: (4R,9S,10S,12R,E)-15-(benzyloxy)-10,12-bis((tert-butyldimethylsilyl)oxy)-4-((triethylsilyl)oxy)-6,9-dimethylpentadec-6-en-8-one
• CAS NO: 1309595-83-2
• Molecular Weight: 749.351
• Mol File: 1309595-83-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,9S,10S,12R,E)-15-(benzyloxy)-10,12-bis((tert-butyldimethylsilyl)oxy)-4-((triethylsilyl)oxy)-6,9-dimethylpentadec-6-en-8-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,9S,10S,12R,E)-15-(benzyloxy)-10,12-bis((tert-butyldimethylsilyl)oxy)-4-((triethylsilyl)oxy)-6,9-dimethylpentadec-6-en-8-one(1309595-83-2)
• EPA Substance Registry System: (4R,9S,10S,12R,E)-15-(benzyloxy)-10,12-bis((tert-butyldimethylsilyl)oxy)-4-((triethylsilyl)oxy)-6,9-dimethylpentadec-6-en-8-one(1309595-83-2)

Safety Data

• Hazardous Substances Data: 1309595-83-2(Hazardous Substances Data)

Upstream product

• 139406-51-2 (R)-2-propylethylene oxide 
• 77118-90-2 2-methyl-4-hydroxy-1-heptene 
• 1309595-81-0 (4R)-2-methyl-4-((triethylsilyl)oxy)hept-1-ene 
• 1003-14-1 2-pentyloxirane 

Downstream Products

• 1309595-66-1 (5R,9R,10R,11S,13R,E)-13-(3-(benzyloxy)propyl)-11-((tertbutyldimethylsilyl)oxy)-3,3-diethyl-7,10,15,15,16,16-hexamethy-5-propyl-4,14-dioxa-3,15-disilaheptadec-7-en-9-ol 
• 1309595-55-8 C₄₄H₈₆O₆Si₃ 

Relevant articles and documents

Highly demanding cross-metathesis in the synthesis of the C16-C30 fragment of dolabelide C

A highly demanding cross-metathesis (CM) reaction for the formation of the C24-C25 trisubstituted olefin of dolabelide C has been optimized. A difference in reactivity between the E and Z enone isomers in this reaction was uncovered, and the selection of the Z isomer of the starting enone was critical for the success of the cross-metathesis. Application to the synthesis of the C16-C30 fragment of dolabelide C is reported.