13307-04-5

Basic information

• Product Name: Silanamine, 1,1,1-trichloro-N,N-dimethyl-
• Synonyms: Silanamine, 1,1,1-trichloro-N,N-dimethyl-
• CAS NO: 13307-04-5
• Molecular Formula: C₂H₆Cl₃NSi
• Molecular Weight: 0
• Mol File: 13307-04-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 116.4°C at 760 mmHg
• Flash Point: 24.2°C
• Appearance: /
• Density: 1.287g/cm³
• Vapor Pressure: 18.2mmHg at 25°C
• Refractive Index: 1.464
• CAS DataBase Reference: Silanamine, 1,1,1-trichloro-N,N-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1,1,1-trichloro-N,N-dimethyl-(13307-04-5)
• EPA Substance Registry System: Silanamine, 1,1,1-trichloro-N,N-dimethyl-(13307-04-5)

Safety Data

• Hazardous Substances Data: 13307-04-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C2H6Cl3NSi/c1-6(2)7(3,4)5/h1-2H3

Upstream product

• 3768-58-9 bis(dimethylamino)dimethylsilane 

Downstream Products

• 13328-30-8 bis(N,N-dimethylamino)dichlorosilane 
• 75-78-5 dimethylsilicon dichloride 
• 13307-05-6 tris(dimethylamino)chlorosilane 

Relevant articles and documents

Complexation and Exchange Reactions of some Dimethylamino-substituted Group 4 Compounds

Reactions of CH2(NMe2)2, (1), SiMe2(NMe2)2, (2), (cp=η-cyclopentadienyl), (3), and , (4), with covalent metal halides MCl4 (M=Ti,Zr,Si,Ge,or Sn) and MCl3 (M=Ti,V,or Cr) fall into two categories: (a) N-donor chelation leading to complex formation and (b) halide-NMe2 exchange.Compound (1) gives 1:1 complexes with MCl4 (M=Ti or Sn) and 2:1 complex with VCl3.Compound (2) provides 1:1 complexes with MCl4 (M=Ti,Zr,Hf, or Sn).The decomposition of TiCl4*SiMe2(NMe2)2 --> invariably occurs in both the solid state and solution.There is no reaction of (2) with metal(III) chlorides.With MCl4 (M=Si or Ge 'scrambling' reactions involving halide-NMe2 exchange occur and these have been monitored by 1H n.m.r. spectroscopy.Reactions of (3) and (4) with MCl4 (M=Si,Ge,Sn,Ti,Zr,or Hf) consistently feature halide-NMe2 exchange rather than adduct formation.All complexes have been characterised by analytical and spectroscopic (1H n.m.r. and i.r.) investigations.