1336-21-6 Usage
Chemical Description
Ammonium hydroxide is a solution of ammonia in water that is used in cleaning products.
Description
Ammonium hydroxide is a colorless, liquid solution with a characteristic and pungent odor. It is ammonia combined with water. Ammonia (NH3) is a compound consisting of nitrogen and hydrogen. Both ammonia and ammonium hydroxide are very common compounds, found naturally in the environment (in air, water, and soil) and in all plants and animals, including humans. Ammonia is a source of nitrogen, an essential element for plants and animals. Ammonia is also produced by the human body – by our organs and tissues and by beneficial bacteria living in our intestines.
Ammonia plays an important role in protein synthesis in the human body. In brief summary, all living things need proteins, which are comprised of some 20 different amino acids. While plants and microorganisms can synthesize most amino acids from the nitrogen in the atmosphere, animals cannot. For humans, some amino acids cannot be synthesized at all and must be consumed as intact amino acids. Other amino acids, however, can be synthesized by microorganisms in the gastrointestinal tract with the help of ammonia ions. Thus, ammonia is a key player in the nitrogen cycle and in protein synthesis. Ammonia also helps maintain the body's pH balance.
Chemical Properties
Ammonium hydroxide exists only in the form of an aqueous solution. The compound is prepared by dissolving NH3 in H2O and usually is referred to in industrial trade as aqua ammonia. For industrial procurements, the concentration of NH3 in solution is normally specified in terms of the specific gravity (degrees Baum′e, °Be). Common concentrations are 20 °Be and 26 °Be. The former is equivalent to a sp gr of 0.933, or a concentration of about 17.8% NH3 in solution; the latter is equivalent to a sp gr of 0.897, or a concentration of about 29.4% NH3. These figures apply at a temperature of 60 °F (15.6 °C). Reagent grade NH4OH usually contains approximately 58% NH4OH (from 28 to 30% NH3 in solution).
Uses
Different sources of media describe the Uses of 1336-21-6 differently. You can refer to the following data:
1. Ammonium hydroxide is widely utilized as a leavening agent or acidity regulator in food production. It serves as a precursor to some alkyl amines and is also used in the tobacco industry for flavor enhancement and as a processing aid. During furniture making, it combines with tannic acid and is used to darken or stain wood by making it iron salts. In chemical laboratories, it used for qualitative inorganic analysis, as a complexant and as a base. It is used to clean gold, silve, and platinum jewelry. It is an active component of Tollens' reagent (consisting of a solution of silver nitrate and ammonia) and is used to determine the presence of aldehyde or alpha-hydroxy ketone functional groups.
2. Ammonium Hydroxide is an alkaline that is a clear, colorless solu-
tion of ammonia which is used as a leavening agent, a ph control
agent, and a surface finishing agent. it is used in baked goods, cheese,
puddings, processed fruits, and in the production of caramels.
3. Ammonium hydroxide is used as a cleaning agent and sanitizer in many household and industrial cleaners. Ammonium hydroxide is also used in the manufacture of products such as fertilizer, plastic, rayon and rubber. Aqueous ammonia is corrosive to aluminum alloys, copper, copper alloys, and galvanized surfaces. Aqueous ammonia is an excellent acid neutralizer.
Definition
Ammonium hydroxide,NH40H, is a hydrate of anunonia and exists in crystalline form at -79°C. Normally, it is only found in an aqueous solution also known as aquaanunonia and anunonia water. It is prepared by dissolving NH3 inH20. Reagent grade anunonium hydroxide contains from 28 to 30% NH3 at 15.6 °C. Industrial sales specify the concentration of NH3 in solution in terms of specific gravity. Common concentrations are 20 °Be, which would bea concentration of 17.8% NH3 (specific gravity 0.933) and 26 °Be (specific gravity 0.897), or a concentration of 29.4% NH3. Ammonium hydroxide is an excellent medium for the reaction of NH3 (which becomes the NH4 radical in solution) with other compounds for the preparation of anunonium salts and other nitrogen-containing chemicals. It is an ingredientin deodorants, etching compounds, and cleaning and bleaching materials. Ammoniumhydroxide, as aqua ammonia, finds wide use as a neutralizing agent,because it is inexpensive and strongly alkaline.
Application
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Industry
Application
Role/benefit
Food processing
Baked goods, cheeses, chocolates, other confectionery (e.g., caramel), and puddings
Leavening agent, pH control agent and surface-finishing agent/safe and weakly alkaline
Meat products
Antimicrobial agent/ lowers the acidity of meet, making it difficult for pathogens to survive
Cleaning
Household and industrial cleansers
Cleansing ingredient/ helps to kill microbial agents like bacteria
Alkaline disinfectant
Main ingredient/disinfects sarin
Agriculture
Manufacture of fertilizers
Source of nitrogen
Chemical manufacture
Manufacture of alkyl amine
Precursor/source of amino
Cosmetics
Hair dyes and colors
pH adjusters/alkaline and safe
Chemical analysis
Determination of certain elements such as copper and nickel
Precipitant/ helps to precipitate various elements
Organic synthesis
Amide coupling reactions
Reagent/source of NH3
SNAr reactions
Nucleophile
Catalytic reduction of nitriles
Additive
Others
Wood staining
Stain agent/better for the wood containing tannic acids
Circuit board manufacturing
Etching agent/has high alkalinity which makes it very corrosive to certain metals
Tobacco processing
Processing aid/enhances tobacco flavor
Treatment of straw for cattle
Produce "ammoniated straw" which is more edible for cattle
Coagulation of natural rubber latex
pH adjusters/helps to stabilize the natural rubber lattices
General Description
Ammonium hydroxide is a colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which arise from the solution) irritate the eyes.
Air & Water Reactions
Water soluble. Generates a small amount of heat when diluted with water.
Reactivity Profile
Ammonium hydroxide reacts exothermically with acids. Evolves toxic gaseous ammonia with strong bases. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. (Thodos, G. Amer. Inst. Chen. Engrs. J., 1964, 10, 274.).
Hazard
Liquid and vapor extremely irritating, especially to eyes.
Health Hazard
Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. Splashes to the eye may be serious, as contact may cause severe burns, irritation pain and possibly blindness. Direct contact with skin may cause severe burns if the chemical is not quickly rinsed away with copious amounts of water. Inhaling mists of ammonium hydroxide may result in irritation of the nose and throat with symptoms including burning, coughing, choking and pain. Inhaling concentrated mist may result in pulmonary edema and shock. Ingesting ammonium hydroxide may cause pain and burns of the esophagus and gastrointestinal tract.
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Flammability and Explosibility
Ammonia vapor is slightly flammable (NFPA rating = 1) and ignites only with
difficulty. Ammonia forms explosive mixtures with air in the range 16 to 25%.
Water, carbon dioxide, or dry chemical extinguishers should be used for ammonia
fires.
Agricultural Uses
Ammonium hydroxide is also known as ammonia
solution, aqua ammonia, aqueous ammonia or
ammonia liquor. It is the solution of ammonia in water
and is commonly referred to as ammonium hydroxide. It
is the simplest nitrogen solution made by forcing
compressed ammonia (anhydrous ammonia) gas into
water.
Safety Profile
A human poison by
ingestion. An experimental poison by
inhalation and ingestion. A severe eye
irritant. Human systemic irritant effects by
ocular and inhalation routes. Mutation data
reported. Incompatible with acrolein,
nitromethane, acrylic acid, chlorosulfonic
acid, dimethyl sulfate, halogens, (Au + aqua
regia), HCl, HF, HNO3, oleum, ppropiolactone,
propylene oxide, AgNO3,
Ag2O, (Ag20 + C2H5OH), AgMn04,
H2SO4. Dangerous; liquid can inflict burns.
Use with adequate ventilation. When
heated to decomposition it emits NH3 and
NO2.
Potential Exposure
It is used in detergents, stain removers,
bleaches, dyes, fibers, and resins.
storage
All work with this substance should be
conducted in a fume hood to prevent exposure by inhalation, and splash goggles and
impermeable gloves should be worn at all times to prevent eye and skin contact.
Containers should be tightly sealed to prevent escape of vapor and should be stored
in a cool area separate from halogens, acids, and oxidizers. Containers stored in
warm locations may build up dangerous internal pressures of ammonia gas.
Shipping
UN2672 Ammonia solutions, relative density
between 0.880 and 0.957 at 15 C in water, with .10% but
not .35% ammonia, Hazard class: 8; Labels: 8-Corrosive
material.
Incompatibilities
Solution is strongly alkaline. Violent
reaction with strong oxidizers, acids (exothermic reaction
with strong mineral acids). Shock-sensitive compounds
may be formed with halogens, mercury oxide; silver oxide.
Fire and explosions may be caused by contact with β-propiolactone,
silver nitrate; ethyl alcoho; silver permanganate;
trimethylammonium amide; 1-chloro-2,4-dinitrobenzene,
o-chloronitrobenzene, platinum, trioxygen difluoride; selenium
difluoride dioxide; boron halides; mercury, chlorine,
iodine; bromine, hypochlorites, chlorine bleach; amides,
organic anhydrides; isocyanates, vinyl acetate; alkylene
oxides; epichlorohydrin; aldehydes. Attacks some coatings,
plastics and rubber. Attacks copper, brass, bronze, aluminum,
steel, zinc, and their alloys.
Waste Disposal
Dilute with water, neutralize
with HCl and discharge to sewer.
Check Digit Verification of cas no
The CAS Registry Mumber 1336-21-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,3,3 and 6 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1336-21:
(6*1)+(5*3)+(4*3)+(3*6)+(2*2)+(1*1)=56
56 % 10 = 6
So 1336-21-6 is a valid CAS Registry Number.
InChI:InChI=1/H3N.H2O/h1H3;1H2
1336-21-6Relevant articles and documents
Electrospun Cu-doped titania nanofibers for photocatalytic hydrolysis of ammonia borane
Yousef, Ayman,Barakat, Nasser A.M.,Kim, Hak Yong
, p. 98 - 106 (2013)
Among reported hydrogen storage materials, ammonia borane is a promising candidate to be utilized in many industrial applications. The high chemical resistance of the ceramic catalysts makes them one of the most stable classes of catalytic materials. In this study, CuO nanoparticles (NPs) -doped TiO 2 nanofibers (NFs) are introduced as a highly effective and reusable catalyst for ammonia borane complex hydrolysis. The incorporation of CuO NPs inside the TiO2 NFs provided distinct advantages for the introduced catalyst; the aggregation problem of the CuO NPs was overcome and a synergistic effect was created as the synthesized CuO NPs-doped TiO2 revealed higher activity compared to the individual components. Typically, after 10 min, the obtained hydrogen equivalent was 2.7, 0.9 and 0.95 when CuO NPs-doped TiO2 nanofibers, CuO NPs and pristine TiO2 nanofibers were used as the catalyst, respectively. The catalytic activity of the introduced nanofibers did not change after being used for three successive cycles. Moreover, the catalytic performance was strongly modified when the hydrolysis process was performed under sunlight irradiation because of the photocatalytic activity of the TiO2 and CuO. The introduced nanofibers were prepared by the simple, effective, low cost and high yielding technique of electrospinning. The present study introduces TiO2 nanofibers as a promising catalyst for the ammonia borane complex, as well as an interesting support used for functional materials.
S-Doped three-dimensional graphene (S-3DG): A metal-free electrocatalyst for the electrochemical synthesis of ammonia under ambient conditions
Wang, Jin,Wang, Shuang,Li, Jinping
, p. 2258 - 2263 (2020)
In this study, we report sulfur-doped three-dimensional graphene (S-3DG) as a metal-free electrocatalyst for N2 reduction reaction (NRR) under ambient conditions. Due to the high electron transport capacity and stable physicochemical properties
Effect of carbon and nitrogen double vacancies on the improved photocatalytic hydrogen evolution over porous carbon nitride nanosheets
Li, Huihui,Ning, Fuchun,Chen, Xiaofei,Shi, Anye
, p. 3270 - 3278 (2021)
Porous carbon nitride nanosheets with carbon and nitrogen double vacancies have been synthesized by a soft template-supported one-pot method. Besides their highly defined and unambiguous structure, they also show minimal thickness and high crystallinity.
In-situ formation of bismuth nanoparticles on nickel foam for ambient ammonia synthesis via electrocatalytic nitrogen reduction
Li, Guangzhe,Pan, Zhefei,Lin, He,An, Liang
, (2021/05/04)
Bismuth has been regarded as a promising electrocatalyst for triggering nitrogen reduction to ammonia, due to the ease of nitrogen dissociation rendered by the strong interaction between Bi 6p band and the N 2p orbitals. However, the poor conductivity of bismuth limits the electron transfer for nitrogen reduction. In addition, the sluggish water dissociation on the bismuth surface leads to insufficient proton supply for the protonation step of *N2, causing inferior ammonia production performance. In this work, we prepare an integrated and binder-free bismuth nanoparticles@nickel foam electrode for ambient ammonia synthesis via a facile displacement reaction. Using nickel foam as the conductive substrate improves the electron transfer of bismuth for nitrogen reduction to ammonia. In addition, enhanced water dissociation on the nickel surface improves the protonation of *N2 by supplying adequate protons via hydrogen spillover, thus boosting the ammonia production performance. This integrated electrode eliminates the use of polymer binders and reduces the contact resistance between the diffusion layer and catalyst layer, facilitating electron delivery and reducing cell resistance, thus requiring less energy input for ammonia production. The performance examination in an electrochemical H-type cell shows that an ammonia yield rate as high as of 9.3 × 10?11 mol s?1 cm?2 and a Faradaic efficiency of 6.3% are achieved. An ammonia yield rate of 8.19 × 10?11 mol s?1 cm?2 is observed after 6 cycles, with a retention rate of 88%.
