1363415-72-8

Basic information

• Product Name: methyl 4-undecanoylbenzoate
• Synonyms: methyl 4-undecanoylbenzoate
• CAS NO: 1363415-72-8
• Molecular Weight: 304.43
• Mol File: 1363415-72-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4-undecanoylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-undecanoylbenzoate(1363415-72-8)
• EPA Substance Registry System: methyl 4-undecanoylbenzoate(1363415-72-8)

Safety Data

• Hazardous Substances Data: 1363415-72-8(Hazardous Substances Data)

Upstream product

• 872-05-9 1-Decene 
• 229648-45-7 methyl 4-(isopropylcarbamoyl)benzoate 
• 20157-33-9 n-decylmagnesium chloride 

Relevant articles and documents

Palladium/NHC (NHC = N-Heterocyclic Carbene)-Catalyzed B-Alkyl Suzuki Cross-Coupling of Amides by Selective N-C Bond Cleavage

A highly chemoselective, palladium-NHC (NHC = N-heterocyclic carbene)-catalyzed, direct cross-coupling between B-sp3-alkyl reagents and activated amides by N-C(O) cleavage is reported. Palladium-NHC precatalysts promote chemoselective alkylations of amides that are inaccessible by applying strong organometallic reagents. Various amides, including challenging primary amides after direct and site-selective N,N-di-Boc activation, are compatible with this method. The potential of this mild protocol is demonstrated in sequential C(sp2)-C(sp2)/C(sp2)-C(sp3) cross-couplings deploying a di-Boc amide derived from a common primary amide bond. The method provides a rare example of air- and moisture-stable, well-defined, and highly reactive Pd-NHC precatalysts in B-alkyl-Suzuki cross-couplings.