137314-81-9

Basic information

• Product Name: 2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone
• Synonyms: 2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone
• CAS NO: 137314-81-9
• Molecular Weight: 265.74
• Mol File: 137314-81-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone(137314-81-9)
• EPA Substance Registry System: 2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone(137314-81-9)

Safety Data

• Hazardous Substances Data: 137314-81-9(Hazardous Substances Data)

Upstream product

• 492-41-1 (1R,2S)-norephedrine 
• 6044-68-4 3,3-dimethoxyprop-1-ene 
• 16251-50-6 (1S,2R)-(+)-2-chloro-N-(2-hydroxy-1-methyl-2-phenylethyl)acetamide 

Downstream Products

• 142954-98-1 (2R,3S,7R,7aS)-7-Iodomethyl-3-methyl-2-phenyl-tetrahydro-pyrrolo[2,1-b]oxazol-5-one 
• 137314-90-0 (2R,3S,7R,7aS)-3,7-Dimethyl-2-phenyl-tetrahydro-pyrrolo[2,1-b]oxazol-5-one 
• 137314-85-3 2-Iodo-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone 

Relevant articles and documents

Stereoselective Radical-Mediated Cyclization of Norephedrine Derived α-Iodoamides: Synthesis of Enantiopure Pyrrolidines and Transition State Modelling

Radical-mediated cyclization of norephedrine derived α-iodoamides 1 was found to be highly stereoselective ( 97:3) favouring diastereoisomer 2.Bicyclic lactams 2 were transformed in high yields into enantiomerically pure pyrrolidines 10.Transition stat