1393678-77-7

Basic information

• Product Name: dimethyl 2-(2-acetylphenyl)malonate
• Synonyms: dimethyl 2-(2-acetylphenyl)malonate
• CAS NO: 1393678-77-7
• Molecular Weight: 250.251
• Mol File: 1393678-77-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dimethyl 2-(2-acetylphenyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-(2-acetylphenyl)malonate(1393678-77-7)
• EPA Substance Registry System: dimethyl 2-(2-acetylphenyl)malonate(1393678-77-7)

Safety Data

• Hazardous Substances Data: 1393678-77-7(Hazardous Substances Data)

Upstream product

• 6773-29-1 dimethyl diazomalonate 
• 3376-33-8 O-methyl acetophenone oxime 

Relevant articles and documents

Rh-Catalyzed Regioselective ortho-C-H Carbenoid Insertion of Diarylazines

The Rh-catalyzed ortho-C-H carbenoid insertion reaction of diarylazines with diazo compounds has been developed. A wide range of ortho-substituted diarylazines have been obtained in moderate to high yields with high regioselectivity at room temperature. The hydrolysis of the products could release ketones or aldehydes, giving access to aromatic 1,5-keto-diesters as valuable synthons for further chemical transformations.