1448251-23-7

Basic information

• Product Name: C₂₈H₂₁CsO₂Pd
• CAS NO: 1448251-23-7
• Molecular Weight: 628.799
• Mol File: 1448251-23-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₈H₂₁CsO₂Pd(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₈H₂₁CsO₂Pd(1448251-23-7)
• EPA Substance Registry System: C₂₈H₂₁CsO₂Pd(1448251-23-7)

Safety Data

• Hazardous Substances Data: 1448251-23-7(Hazardous Substances Data)

Upstream product

• 1464815-30-2 C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾ 
• 39477-86-6 1-phenyl-1-(2-hydroxyphenyl)ethene 

Downstream Products

• 29909-72-6 3-Phenylbenzofuran 
• 1464815-30-2 C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾ 

Relevant articles and documents

Palladium(II)-catalyzed direct carboxylation of alkenyl C-H bonds with CO2

Pd-catalyzed direct carboxylation of alkenyl C-H bonds with carbon dioxide was realized for the first time. Treatment of 2-hydroxystyrenes and a catalytic amount of Pd(OAc)2 with Cs2CO3 under atmospheric pressure of CO2 afforded corresponding coumarins in good yield. Furthermore, isolation of the key alkenylpalladium intermediate via C-H bond cleavage was achieved. The reaction was proposed to undergo reversible nucleophilic addition of the alkenylpalladium intermediate to CO2.