1464815-30-2

Basic information

• Product Name: C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾
• Synonyms: C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾
• CAS NO: 1464815-30-2
• Molecular Weight: 328.146
• Mol File: 1464815-30-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾(1464815-30-2)
• EPA Substance Registry System: C₁₄H₁₁O^(1-)*Cs⁽¹⁺⁾(1464815-30-2)

Safety Data

• Hazardous Substances Data: 1464815-30-2(Hazardous Substances Data)

Upstream product

• 2206-27-1 dimethylsulfoxide-d6 
• 124-38-9 carbon dioxide 
• 1448251-23-7 C₂₈H₂₁CsO₂Pd 
• 39477-86-6 1-phenyl-1-(2-hydroxyphenyl)ethene 
• 108-86-1 bromobenzene 
• 118-93-4 o-hydroxyacetophenone 
• 58972-42-2 1-(2-hydroxyphenyl)-1-phenyl-ethanol 

Downstream Products

• 1448251-23-7 C₂₈H₂₁CsO₂Pd 

Relevant articles and documents

Palladium(II)-catalyzed direct carboxylation of alkenyl C-H bonds with CO2

Pd-catalyzed direct carboxylation of alkenyl C-H bonds with carbon dioxide was realized for the first time. Treatment of 2-hydroxystyrenes and a catalytic amount of Pd(OAc)2 with Cs2CO3 under atmospheric pressure of CO2 afforded corresponding coumarins in good yield. Furthermore, isolation of the key alkenylpalladium intermediate via C-H bond cleavage was achieved. The reaction was proposed to undergo reversible nucleophilic addition of the alkenylpalladium intermediate to CO2.